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Ce(CO)OH诱导增强多孔碳的微波吸收性能

Enhancement of microwave absorption performance of porous carbon induced by Ce (CO) OH.

作者信息

Wang Jijun, Chen Yuhua, Wei Yaxing, Li Yan, Li Fangyuan, Li Bingzhen, Wu Qingqing, Zhao Jinlong

机构信息

Chinese People's Liberation Army, Beijing, China.

Institute of Defense Engineering, Academy of Military Sciences, Beijing, China.

出版信息

Front Chem. 2023 Jan 9;10:1100111. doi: 10.3389/fchem.2022.1100111. eCollection 2022.

Abstract

In recent years, electromagnetic pollution has become more and more serious, resulting in a very negative impact on people's health. Therefore, it is important to develop efficient microwave absorbers to reduce electromagnetic pollution. Here, we construct a novel absorbing material of the polymer gel-derived porous carbon decorated by rare earth compounds (Ce (CO) OH). When the thickness is 2.2 mm, the composite exhibits excellent microwave absorption performance with the optimal RL value and EAB reached up to -47.67 dB and 5.52 GHz, respectively, covering the Ku band. The high-efficiency microwave absorption is mainly attributed to the synergistic effect of dipole polarization, defect polarization and interfacial polarization. This work not only provides a new view for designing superior absorber materials, but also lay a foundation for their real applications.

摘要

近年来,电磁污染日益严重,对人们的健康产生了非常负面的影响。因此,开发高效的微波吸收剂以减少电磁污染具有重要意义。在此,我们构建了一种新型的吸收材料,即由稀土化合物(Ce(CO)OH)修饰的聚合物凝胶衍生多孔碳。当厚度为2.2毫米时,该复合材料表现出优异的微波吸收性能,最佳反射损耗值和有效吸收带宽分别达到-47.67分贝和5.52吉赫兹,覆盖Ku波段。高效的微波吸收主要归因于偶极极化、缺陷极化和界面极化的协同效应。这项工作不仅为设计优异的吸收剂材料提供了新的视角,也为其实际应用奠定了基础。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3546/9870177/4d26eed44778/fchem-10-1100111-g001.jpg

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