School of Microelectronics, Fudan University, Shanghai 200433, People's Republic of China.
Hubei Yangtze Memory Laboratories, Wuhan 430205, People's Republic of China.
Nanotechnology. 2023 Feb 13;34(17). doi: 10.1088/1361-6528/acb653.
Ferroelectric field effect transistor (FeFET) memories with hafnium zirconium oxide (HZO) ferroelectric gate dielectric and ultrathin InOchannel exhibit promising applicability in monolithic three-dimensional (M3D) integrated chips. However, the inferior stability of the devices severely limits their applications. In this work, we studied the effect of single cycle of atomic-layer-deposited Al-O bonds repeatedly embedded into an ultrathin InOchannel (∼2.8 nm) on the HfZrOFeFET memory performance. Compared to the pure InOchannel, three cycles of Al-O bonds modified InOchannel (IAO-3) generates a much larger memory window (i.e. drain current ratio between the programmed and erased devices) under the same program conditions (+5.5 V/500 ns), especially after post-annealing at 325 °C for 180 s in O(1238 versus 317). Meanwhile, the annealed IAO-3 FeFET memory also shows quite stable data retention up to 10s, and much more robust program/erase stabilities till 10cycles. This is because the modification of strong Al-O bonds stabilizes the oxygen vacancies and reduces the bulk trap density in the channel. Furthermore, it is indicated that the program and erase efficiencies increase gradually with reducing the channel length of the memory device. By demonstrating markedly improved performance of the HZO FeFET memory with the ultrathin IAO-3 channel, this work provides a promising device for M3D integratable logic and memory convergent systems.
具有氧化铪锆(HZO)铁电栅介质和超薄 InO 沟道的铁电场效应晶体管(FeFET)存储器在单片三维(M3D)集成芯片中具有很有前景的适用性。然而,器件的稳定性较差严重限制了它们的应用。在这项工作中,我们研究了将原子层沉积的 Al-O 键单循环反复嵌入到超薄 InO 沟道(∼2.8nm)中对 HfZrOFeFET 存储器性能的影响。与纯 InO 沟道相比,经过三周期 Al-O 键修饰的 InO 沟道(IAO-3)在相同编程条件(+5.5V/500ns)下产生更大的存储窗口(即编程和擦除器件之间的漏电流比),尤其是在 325°C 下退火 180s 后在 O(1238 对 317)。同时,退火后的 IAO-3 FeFET 存储器在 10s 内也表现出相当稳定的数据保持能力,并且在 10 个周期内具有更好的编程/擦除稳定性。这是因为强 Al-O 键的修饰稳定了氧空位并降低了沟道中的体陷阱密度。此外,研究表明,随着存储器件沟道长度的减小,编程和擦除效率逐渐提高。通过展示具有超薄 IAO-3 沟道的 HZO FeFET 存储器性能的显著改善,这项工作为 M3D 可集成逻辑和存储融合系统提供了一种有前途的器件。