Single-Walled Zeolitic Nanotubes: Advantaged Supports for Poly(ethylenimine) in CO Separation from Simulated Air and Flue Gas.

Previous research has demonstrated that amine polymers rich in primary and secondary amines supported on mesoporous substrates are effective, selective sorbent materials for removal of CO from simulated flue gas and air. Common substrates used include mesoporous alumina and silica (such as SBA-15 and MCM-41). Conventional microporous materials are generally less effective, since the pores are too small to support low volatility amines. Here, we deploy our newly discovered zeolite nanotubes, a first-of-their-kind quasi-1D hierarchical zeolite, as a substrate for poly(ethylenimine) (PEI) for CO capture from dilute feeds. PEI is impregnated into the zeolite at specific organic loadings. Thermogravimetric analysis and porosity measurements are obtained to determine organic loading, pore filling, and surface area of the supported PEI prior to CO capture studies. MCM-41 with comparable pore size and surface area is also impregnated with PEI to provide a benchmark material that allows for insight into the role of the zeolite nanotube intrawall micropores on CO uptake rates and capacities. Over a range of PEI loadings, from 20 to 70 w/w%, the zeolite allows for increased CO capture capacity over the mesoporous silica by ∼25%. Additionally, uptake kinetics for nanotube-supported PEI are roughly 4 times faster than that of a comparable PEI impregnated in SBA-15. It is anticipated that this new zeolite will offer numerous opportunities for engineering additional advantaged reaction and separation processes.