构建基于钴卟啉的金属-有机框架用于芳基硼酸的光催化有氧氧化为酚类化合物。
Building a cobaloxime-based metal-organic framework for photocatalytic aerobic oxidation of arylboronic acids to phenols.
机构信息
Department of Chemistry and Key Laboratory for Preparation and Application of Ordered Structural Materials of Guangdong Province, Shantou University, Guangdong 515063, China.
Department of Medicinal Chemistry, Shantou University Medical College, Shantou, Guangdong 515041, China.
出版信息
Chem Commun (Camb). 2023 Feb 21;59(16):2239-2242. doi: 10.1039/d2cc06945h.
Herein, the design and synthesis of an unprecedented cobaloxime-based zirconium metal-organic framework (Zr-TCPCo) with an net is reported. This heterogeneous material as a photocatalyst exhibits excellent catalytic activity for aerobic oxidation of arylboronic acids to phenols. Recycling experiments demonstrate the stability and reusability of Zr-TCPCo as a robust catalyst.
本文报道了一种前所未有的基于钴卟啉的锆基金属有机骨架（Zr-TCPCo）的设计与合成。这种多相光催化剂对芳基硼酸氧化为苯酚表现出优异的催化活性。回收实验证明了 Zr-TCPCo 作为一种稳定且可重复使用的催化剂的稳定性和可再生性。
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