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室温下金属玻璃的独特弛豫机制。

Distinct relaxation mechanism at room temperature in metallic glass.

机构信息

Institute of Physics, Chinese Academy of Sciences, 100190, Beijing, China.

Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China.

出版信息

Nat Commun. 2023 Feb 1;14(1):540. doi: 10.1038/s41467-023-36300-x.

Abstract

How glasses relax at room temperature is still a great challenge for both experimental and simulation studies due to the extremely long relaxation time-scale. Here, by employing a modified molecular dynamics simulation technique, we extend the quantitative measurement of relaxation process of metallic glasses to room temperature. Both energy relaxation and dynamics, at low temperatures, follow a stretched exponential decay with a characteristic stretching exponent β = 3/7, which is distinct from that of supercooled liquid. Such aging dynamics originates from the release of energy, an intrinsic nature of out-of-equilibrium system, and manifests itself as the elimination of defects through localized atomic strains. This finding is also supported by long-time stress-relaxation experiments of various metallic glasses, confirming its validity and universality. Here, we show that the distinct relaxation mechanism can be regarded as a direct indicator of glass transition from a dynamic perspective.

摘要

由于弛豫时间尺度极长,室温下眼镜如何放松仍然是实验和模拟研究的一大挑战。在这里,我们通过采用改进的分子动力学模拟技术,将金属玻璃弛豫过程的定量测量扩展到室温。在低温下,能量弛豫和动力学都遵循具有特征拉伸指数β=3/7 的扩展指数衰减,这与过冷液体不同。这种老化动力学源于能量的释放,这是非平衡系统的固有性质,表现为通过局部原子应变消除缺陷。这一发现也得到了各种金属玻璃的长时间应力松弛实验的支持,证实了其有效性和普遍性。在这里,我们表明,从动力学角度来看,这种独特的弛豫机制可以被视为玻璃转变的直接指标。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/adc6/9892575/583b9f6ba8e0/41467_2023_36300_Fig1_HTML.jpg

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