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二维和集成钙钛矿异质结构中的能量和电荷转移趋势。

Trends in energy and charge transfer in 2D and integrated perovskite heterostructures.

机构信息

Department of Intelligent Mechatronics Engineering, Sejong University, Seoul 05006, South Korea.

Nanotechnology Research Laboratory, Faculty of Engineering Sciences, GIK Institute of Engineering Sciences and Technology, Topi 23640, Khyber Pakhtunkhwa, Pakistan.

出版信息

Nanoscale. 2023 Feb 23;15(8):3610-3629. doi: 10.1039/d2nr07141j.

Abstract

Two-dimensional (2D) van der Waals (vdW) heterostructured transition metal dichalcogenides (TMDs) open up new possibilities for a wide range of optoelectronic applications. Interlayer couplings are responsible for several fascinating physics phenomena, which are in addition to the multifunctionalities that have been discovered in the field of optoelectronics. These couplings can influence the overall charge, or the energy transfer processes stacking, separation, and dielectric angles. This focused review article summarizes the most recent and promising strategies for interlayer exciton emission in 2D or integrated perovskites and TMD heterostructures. These types of devices require a thorough comprehension and effective control of interlayer couplings in order to realize their functionalities and improve performance, which is demonstrated in this article with the energy or charge transfer mechanisms in the individual devices. An ideal platform for examining the interlayer coupling and the related physical processes is provided by a summary of the recent research findings in 2D perovskites and TMDs. Furthermore, it would encourage more investigation into the comprehension and regulation of excitonic effects and the related optoelectronic applications in vdW heterostructures over a broad spectral response range. Finally, the current challenges and prospects are summarized in this paper.

摘要

二维(2D)范德华(vdW)异质结构过渡金属二卤化物(TMD)为广泛的光电应用开辟了新的可能性。层间耦合负责几种迷人的物理现象,除了在光电领域发现的多功能性之外。这些耦合可以影响整体电荷或能量转移过程堆叠、分离和介电角度。本文总结了最近在二维或集成钙钛矿和 TMD 异质结构中实现层间激子发射的最有前途的策略。这些类型的器件需要彻底理解和有效控制层间耦合,以实现其功能并提高性能,本文通过单个器件中的能量或电荷转移机制证明了这一点。本文总结了二维钙钛矿和 TMD 的最新研究结果,为研究层间耦合和相关物理过程提供了理想的平台。此外,这将鼓励更多地研究在宽光谱响应范围内理解和调节激子效应以及相关的光电子应用在 vdW 异质结构中的作用。最后,本文总结了当前的挑战和展望。

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