Metal-Organic Framework-Based Colloidal Particle Synthesis, Assembly, and Application.

Metal-organic frameworks (MOFs) assembled from metal nodes and organic ligands have received significant attention over the past two decades for their fascinating porous properties and broad applications. Colloidal MOFs (CMOFs) not only inherit the intrinsic properties of MOFs, but can also serve as building blocks for self-assembly to make functional materials. Compared to bulk MOFs, the colloidal size of CMOFs facilitates further manipulation of CMOF particles in a single or collective state in a liquid medium. The resulting crystalline order obtained by self-assembly in position and orientation can effectively improve performance. In this review, we summarize the latest developments of CMOFs in synthesis strategies, self-assembly methods, and related applications. Finally, we discuss future challenges and opportunities of CMOFs in synthesis and assembly, by which we hope that CMOFs can be further developed into new areas for a wider range of applications.