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一种无机荧光化学传感器:合理设计与选择性镁检测

An Inorganic Fluorescent Chemosensor: Rational Design and Selective Mg Detection.

作者信息

Gerard Theodore, Wei Yang, Weerawardhana Erwin, Lugosan Adriana, Zeller Matthias, Dickie Diane A, Li Pengfei, Lee Wei-Tsung

机构信息

Department of Chemistry and Biochemistry, Loyola University Chicago, Chicago, Illinois 60660, United States.

Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, United States.

出版信息

ACS Omega. 2023 Jan 19;8(4):3835-3841. doi: 10.1021/acsomega.2c06058. eCollection 2023 Jan 31.

Abstract

A Zn based complex, , displays greatly increased fluorescence emission in the presence of Mg. Fluorescent and computational studies suggest that selectively interacts with Mg due to optimal cavity size formation between two uncoordinated pyrazole side arms. This work thus represents a new approach to the development of fluorescent chemosensors.

摘要

一种锌基配合物,在镁存在的情况下荧光发射大幅增强。荧光和计算研究表明,由于两个未配位的吡唑侧臂之间形成了最佳的空腔尺寸,该配合物与镁发生选择性相互作用。因此,这项工作代表了一种开发荧光化学传感器的新方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a10f/9893466/7320991a9cb8/ao2c06058_0002.jpg

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