Cherniak A Ia, Antonov K V, Kochetkov N K
Bioorg Khim. 1987 Jul;13(7):958-66.
Di-, tri- and tetrasaccharide fragments of the linear chain of the capsular polysaccharide of Streptococcus pneumoniae type 3 consisting of glucose and glucuronic acid residues connected with beta 1----3- and beta 1----4-glycosidic linkage have been synthesised. A new method for selective deprotection of C3-hydroxyl group in the glucopyranuronic acid moiety is proposed.
已合成了由葡萄糖和葡萄糖醛酸残基通过β1----3-和β1----4-糖苷键相连的3型肺炎链球菌荚膜多糖线性链的二糖、三糖和四糖片段。提出了一种对吡喃葡萄糖醛酸部分中C3-羟基进行选择性脱保护的新方法。