Song Junnan, Vikulina Anna S, Parakhonskiy Bogdan V, Skirtach Andre G
Nano-BioTechnology Group, Department of Biotechnology, Faculty of Bioscience Engineering, Ghent University, Ghent, Belgium.
Bavarian Polymer Institute, Friedrich-Alexander-Universität Erlangen-Nürnberg, Bayreuth, Germany.
Front Chem. 2023 Jan 25;11:1078840. doi: 10.3389/fchem.2023.1078840. eCollection 2023.
Hybrid materials or hybrids incorporating organic and inorganic constituents are emerging as a very potent and promising class of materials due to the diverse but complementary nature of their properties. This complementarity leads to a perfect synergy of properties of the desired materials and products as well as to an extensive range of their application areas. Recently, we have overviewed and classified hybrid materials describing inorganics--organics in Part-I (Saveleva, et al., Front. Chem., 2019, 7, 179). Here, we extend that work in Part-II describing organics--inorganics, i.e., inorganic materials modified by organic moieties, their structure and functionalities. Inorganic constituents comprise of colloids/nanoparticles and flat surfaces/matrices comprise of metallic (noble metal, metal oxide, metal-organic framework, magnetic nanoparticles, alloy) and non-metallic (minerals, clays, carbons, and ceramics) materials; while organic additives can include molecules (polymers, fluorescence dyes, surfactants), biomolecules (proteins, carbohydtrates, antibodies and nucleic acids) and even higher-level organisms such as cells, bacteria, and microorganisms. Similarly to what was described in Part-I, we look at similar and dissimilar properties of organic-inorganic materials summarizing those bringing complementarity and composition. A broad range of applications of these hybrid materials is also presented whose development is spurred by engaging different scientific research communities.
由于有机和无机成分的混合材料(或杂化材料)具有多样但互补的性质,它们正成为一类极具潜力和前景的材料。这种互补性使得所需材料和产品的性能实现完美协同,同时也带来了广泛的应用领域。最近,我们在第一部分(萨韦列娃等人,《化学前沿》,2019年,第7卷,第179页)中对描述无机 - 有机的杂化材料进行了综述和分类。在此,我们在第二部分扩展这项工作,描述有机 - 无机材料,即由有机部分改性的无机材料、它们的结构和功能。无机成分包括胶体/纳米颗粒,平面表面/基质包括金属(贵金属、金属氧化物、金属有机框架、磁性纳米颗粒、合金)和非金属(矿物、粘土、碳和陶瓷)材料;而有机添加剂可以包括分子(聚合物、荧光染料、表面活性剂)、生物分子(蛋白质、碳水化合物、抗体和核酸),甚至包括细胞、细菌和微生物等更高级别的生物体。与第一部分所描述的类似,我们考察有机 - 无机材料的相似和不同性质,总结那些带来互补性和组成的性质。还介绍了这些杂化材料的广泛应用,不同科研群体的参与推动了它们的发展。
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