Time-Varying Pattern and Prediction Model for Geopolymer Mortar Performance under Seawater Immersion.

In this study, immersion experiments were conducted on the geopolymer mortar (GPM) by using artificial seawater, and the effects of alkali equivalent (AE) and waterglass modulus (WGM) on the resistance of geopolymer mortar (GPM) to seawater immersion were analyzed. The test subjected 300 specimens to 270 days of artificial seawater immersion and periodic performance tests. Alkali equivalent (AE) (3-15%) and waterglass modulus (WGM) (1.0-1.8) were employed as influencing factors, and the mass loss and uniaxial compressive strength (UCS) were used as the performance evaluation indexes, combined with X-ray diffraction (XRD) and scanning electron microscopy (SEM) to analyze the time-varying pattern of geopolymer mortar (GPM) performance with seawater immersion. The findings demonstrated a general trend of initially growing and then declining in the uniaxial compression strength (UCS) of geopolymer mortar (GPM) under seawater immersion. The resistance of geopolymer mortar (GPM) to seawater immersion decreased with both higher or lower alkali equivalent (AE), and the ideal range of alkali equivalent (AE) was 9-12%. The diffusion layer of the bilayer structure of the waterglass particle became thinner with an increase in waterglass modulus (WGM), which ultimately led to the reduction in the resistance of the geopolymer structure to seawater immersion. Additionally, a support vector regression (SVR) model was developed based on the experimental data to predict the uniaxial compression strength (UCS) of GPM under seawater immersion. The model performed better and was able to achieve accurate prediction within 1-2 months, and provided an accurate approach to predicting the strength of geopolymer materials in a practical offshore construction project.