Dubdub Ibrahim
Department of Chemical Engineering, King Faisal University, Al-Hassa 31982, Saudi Arabia.
Polymers (Basel). 2023 Jan 18;15(3):494. doi: 10.3390/polym15030494.
Among machine learning (ML) studies, artificial neural network (ANN) analysis is the most widely used technique in pyrolysis research. In this work, the pyrolysis of polypropylene (PP) polymers was established using a thermogravimetric analyzer (TGA) with five sets of heating rates (5-40 K min). TGA data was used to exploit an ANN network by achieving a feed-forward backpropagation optimization technique in order to predict the weight-left percentage. Two important ANN model input variables were identified as the heating rate (K min) and temperature (K). For the range of TGA values, a 2-10-10-1 network with two hidden layers (Logsig-Tansig) was concluded to be the best structure for predicting the weight-left percentage. The ANN demonstrated a good agreement between the experimental and calculated values, with a high correlation coefficient (R) of greater than 0.9999. The final network was then simulated with the new input data set for effective performance. In addition, a sensitivity analysis was performed to identify the uncertainties associated with the relationship between the output and input parameters. Temperature was found to be a more sensitive input parameter than the heating rate on the weight-left percentage calculation.
在机器学习(ML)研究中,人工神经网络(ANN)分析是热解研究中应用最广泛的技术。在这项工作中,使用热重分析仪(TGA)在五组加热速率(5 - 40 K/min)下对聚丙烯(PP)聚合物进行热解。通过采用前馈反向传播优化技术利用TGA数据来开发ANN网络,以预测剩余重量百分比。确定了两个重要的ANN模型输入变量为加热速率(K/min)和温度(K)。对于TGA值范围,得出具有两个隐藏层(Logsig - Tansig)的2 - 10 - 10 - 1网络是预测剩余重量百分比的最佳结构。ANN表明实验值和计算值之间具有良好的一致性,相关系数(R)大于0.9999。然后用新的输入数据集对最终网络进行模拟以实现有效性能。此外,进行了敏感性分析以确定与输出和输入参数之间关系相关的不确定性。发现在计算剩余重量百分比时,温度是比加热速率更敏感的输入参数。