Laboratorio de Materiales Avanzados, Departamento de Química Inorgánica - Instituto Universitario de Materiales de Alicante Universidad de Alicante, E-03080, Alicante, Spain.
KAUST Catalysis Center, King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia.
Small Methods. 2023 Apr;7(4):e2201413. doi: 10.1002/smtd.202201413. Epub 2023 Feb 15.
Metal-organic frameworks (MOFs) are porous hybrid materials with countless potential applications. Most of these rely on their porous structure, tunable composition, and the possibility of incorporating and expanding their functions. Although functionalization of the inner surface of MOF crystals has received considerable attention in recent years, methods to functionalize selectively the outer crystal surface of MOFs are developed to a lesser extent, despite their importance. This article summarizes different types of post-synthetic modifications and possible applications of modified materials such as: catalysis, adsorption, drug delivery, mixed matrix membranes, and stabilization of porous liquids.
金属-有机骨架（MOFs）是具有无数潜在应用的多孔混合材料。其中大多数依赖于其多孔结构、可调节的组成以及可以掺入和扩展其功能的可能性。尽管 MOF 晶体的内表面功能化近年来受到了相当多的关注，但对外晶体表面进行选择性功能化的方法却发展得较少，尽管它们很重要。本文总结了不同类型的后合成修饰方法和改性材料的可能应用，如：催化、吸附、药物传递、混合基质膜和多孔液体的稳定化。
