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3-(2-溴乙基)-5,5-二苯基咪唑烷-2,4-二酮

3-(2-Bromo-eth-yl)-5,5-di-phenyl-imidazolidine-2,4-dione.

作者信息

Guerrab Walid, El Moutaouakil Ala Allah Abderrazzak, Alsubari Abdulsalam, Mague Joel T, Ramli Youssef

机构信息

Laboratory of Medicinal Chemistry, Drug Sciences Research Center, Faculty of Medicine and Pharmacy, Mohammed V University in Rabat, Morocco.

Laboratory of Medicinal Chemistry, Faculty of Clinical Pharmacy, 21 September University, Yemen.

出版信息

IUCrdata. 2023 Jan 26;8(Pt 1):x230060. doi: 10.1107/S2414314623000603. eCollection 2023 Jan.

DOI:10.1107/S2414314623000603
PMID:36794060
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC9912319/
Abstract

The imidazolidine ring in the title mol-ecule, CHBrNO, is slightly ruffled [r.m.s. deviation = 0.0192 Å], while the attached phenyl rings at the C atom at the position between the amine and carbonyl centres are rotated well out of its mean plane [dihedral angles with the imidazolidine ring = 63.60 (8) and 76.4 (1)°]. In the crystal, a three-dimensional network features N-H⋯O and C-H⋯O hydrogen bonds together with C-H⋯π(ring) inter-actions.

摘要

标题分子CHBrNO中的咪唑烷环略有褶皱[r.m.s.偏差 = 0.0192 Å]，而连接在胺基和羰基中心之间位置的C原子上的苯环则很好地旋转出其平均平面[与咪唑烷环的二面角 = 63.60 (8) 和76.4 (1)°]。在晶体中，三维网络具有N-H⋯O和C-H⋯O氢键以及C-H⋯π(环)相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dee0/9912319/8b40fc070b9d/x-08-x230060-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dee0/9912319/03077d01ccd0/x-08-x230060-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dee0/9912319/c4d3b10fdb9d/x-08-x230060-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dee0/9912319/8b40fc070b9d/x-08-x230060-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dee0/9912319/03077d01ccd0/x-08-x230060-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dee0/9912319/c4d3b10fdb9d/x-08-x230060-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/dee0/9912319/8b40fc070b9d/x-08-x230060-fig3.jpg

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