Department of Analytical Chemistry, University of Belgrade-Faculty of Chemistry, PO Box 51, 11158, Belgrade, Serbia.
University of Belgrade-Faculty of Biology, Studentski trg 16, 11000, Belgrade, Serbia.
Chem Biodivers. 2023 Mar;20(3):e202201140. doi: 10.1002/cbdv.202201140. Epub 2023 Mar 3.
Propolis is a resinous natural substance collected by honeybees from different plant sources. The element content of propolis is influenced by the content of elements in the soil, climatic factors, and the degree of pollution. The aim of the study was to characterize element composition and content of toxic elements in 51 propolis collected from different locations in Serbia and to evaluate the differences among them. Determination of the 21 elements were performed using Inductively coupled plasma - optical emission spectrometry. K was the most abundant element, followed by Ca, Mg, Si, Fe, Zn, and Al. The microelements B, Ba, Mn, Na, Pb, and Ti were also present in propolis, while Co, Cr, Cu, Mo, Ni, Sr, and V were found in trace. Toxic elements such as Pb, As, and Cd were found in the trace. Kruskal-Wallis tests differentiate groups of samples by geographical origin. The presence of B, Fe, Sr, Ti, Zn, and As demonstrated statistical significance between six regions of Serbia.
蜂胶是蜜蜂从不同植物源采集的树脂状天然物质。蜂胶的元素含量受土壤元素含量、气候因素和污染程度的影响。本研究的目的是表征来自塞尔维亚不同地区的 51 种蜂胶中有毒元素的元素组成和含量,并评估它们之间的差异。使用电感耦合等离子体-光学发射光谱法测定了 21 种元素。K 是最丰富的元素,其次是 Ca、Mg、Si、Fe、Zn 和 Al。蜂胶中还存在微量元素 B、Ba、Mn、Na、Pb 和 Ti,而 Co、Cr、Cu、Mo、Ni、Sr 和 V 则以痕量存在。痕量的有毒元素如 Pb、As 和 Cd 也被发现。Kruskal-Wallis 检验通过地理来源对样品进行分组。B、Fe、Sr、Ti、Zn 和 As 的存在在塞尔维亚的六个地区之间具有统计学意义。