Shin Wonjun, Jeong Yujeong, Kim Mingyu, Lee Jungsoo, Koo Ryun-Han, Hong Seongbin, Jung Gyuweon, Kim Jae-Joon, Lee Jong-Ho
Department of Electrical and Computer Engineering, Inter-University Semiconductor Research Center, Seoul National University, Seoul, 08826, South Korea.
Discov Nano. 2023 Feb 25;18(1):24. doi: 10.1186/s11671-023-03801-z.
The need for high-performance gas sensors is driven by concerns over indoor and outdoor air quality, and industrial gas leaks. Due to their structural diversity, vast surface area, and geometric tunability, metal oxides show significant potential for the development of gas sensing systems. Despite the fact that several previous reports have successfully acquired a suitable response to various types of target gases, it remains difficult to maintain the reliability of metal oxide-based gas sensors. In particular, the degradation of the sensor platform under repetitive operation, such as off-state stress (OSS) causes significant reliability issues. We investigate the impact of OSS on the gas sensing performances, including response, low-frequency noise, and signal-to-noise ratio of horizontal floating-gate field-effect-transistor (FET)-type gas sensors. The 1/f noise is increased after the OSS is applied to the sensor because the gate oxide is damaged by hot holes. Therefore, the SNR of the sensor is degraded by the OSS. We applied a self-curing method based on a PN-junction forward current at the body-drain junction to repair the damaged gate oxide and improve the reliability of the sensor. It has been demonstrated that the SNR degradation caused by the OSS can be successfully recovered by the self-curing method.
对高性能气体传感器的需求源于对室内外空气质量以及工业气体泄漏的担忧。由于金属氧化物具有结构多样性、巨大的表面积和几何可调节性,它们在气体传感系统的开发中显示出巨大潜力。尽管此前有几份报告已成功实现对各种类型目标气体的适当响应,但要维持基于金属氧化物的气体传感器的可靠性仍然困难。特别是,传感器平台在重复操作(如关态应力(OSS))下的退化会导致严重的可靠性问题。我们研究了OSS对水平浮栅场效应晶体管(FET)型气体传感器的气体传感性能的影响,包括响应、低频噪声和信噪比。将OSS施加到传感器上后,1/f噪声会增加,因为栅极氧化物会被热空穴损坏。因此,传感器的信噪比会因OSS而降低。我们应用了一种基于体-漏结处PN结正向电流的自修复方法来修复受损的栅极氧化物并提高传感器的可靠性。结果表明,通过自修复方法可以成功恢复由OSS导致的信噪比下降。