Zhang Deqi, Guo Shenghui, Gao Jiyun, Yang Li, Zhu Ye, Ma Yanjia, Hou Ming
State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming University of Science and Technology, Kunming 650093, China.
Faculty of Metallurgical and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China.
Materials (Basel). 2023 Feb 11;16(4):1517. doi: 10.3390/ma16041517.
In this paper, with the help of the method of composite materials science, parallel synthesis and high-throughput screening were used to prepare gas sensors with different molar ratios of rare earths and precious metals modified InO, which could be used to monitor and warn the early leakage of gasoline and diesel. Through high-throughput screening, it is found that the effect of rare earth metal modification on gas sensitivity improvement is better than other metals, especially 0.5 mol% Gd modified InO (GdIn) gas sensor has a high response to 100 ppm gasoline (/ = 6.1) and diesel (/ = 5) volatiles at 250 °C. Compared with the existing literature, the sensor has low detection concentration and suitable stability. This is mainly due to the alteration of surface chemisorption oxygen caused by the catalysis and modification of rare earth itself.
本文借助复合材料科学方法,采用平行合成和高通量筛选手段制备了不同稀土与贵金属摩尔比改性InO的气敏传感器,用于监测和预警汽油与柴油的早期泄漏。通过高通量筛选发现,稀土金属改性对提高气敏性的效果优于其他金属,尤其是0.5 mol% Gd改性的InO(GdIn)气敏传感器在250℃下对100 ppm汽油(/ = 6.1)和柴油(/ = 5)挥发物具有高响应。与现有文献相比,该传感器具有低检测浓度和适宜的稳定性。这主要归因于稀土自身的催化和改性导致表面化学吸附氧的改变。