分步组装异金属、异双齿“三联型”Janus 型金属有机多面体。
Stepwise assembly of heterometallic, heteroleptic "triblock Janus-type" metal-organic polyhedra.
机构信息
Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, and The Barcelona Institute of Science and Technology, Campus UAB, Bellaterra, Barcelona 08193, Spain.
Departament de Química, Facultat de Ciències Universitat Autònoma de Barcelona, Bellaterra 08193, Spain.
出版信息
Chem Commun (Camb). 2023 Mar 16;59(23):3423-3426. doi: 10.1039/d2cc06815j.
Increasing the chemical complexity of metal-organic cages (MOCs) or polyhedra (MOPs) demands control over the simultaneous organization of diverse organic linkers and metal ions into discrete caged structures. Herein, we show that a pre-assembled complex of the archetypical cuboctahedral MOP can be used as a template to replicate such caged structure, one having a "triblock Janus-type" configuration that is both heterometallic and heteroleptic.
提高金属-有机笼（MOCs）或多面体（MOPs）的化学复杂度需要控制各种有机配体和金属离子同时组织成离散的笼状结构。在此，我们展示了可以使用典型的立方八面体 MOP 的预组装配合物作为模板来复制这种笼状结构，该结构具有“三嵌段 Janus 型”构型，是异金属和异配位的。
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