Department of Chemistry, Taras Shevchenko National University of Kyiv, Volodymyrska St. 64, Kyiv 01601, Ukraine.
Department of Inorganic Polymers, Petru Poni Institute of Macromolecular Chemistry, Aleea Grigore Ghica Voda 41-A, Iasi 700487, Romania.
Chem Commun (Camb). 2022 May 10;58(38):5745-5748. doi: 10.1039/d2cc01364a.
This study describes the synthesis of the first aziridinium-based compounds, namely hybrid perovskites (AzrH)PbHal (where AzrH = aziridinium, Hal = Cl, Br or I). This highly reactive species was stabilized in 3D lead halide frameworks and was found to be a small enough organic cation to promote the formation of semiconducting organo-inorganic materials.
本研究描述了首例氮丙啶基化合物的合成，即杂化钙钛矿（AzrH）PbHal（其中 AzrH = 氮丙啶，Hal = Cl、Br 或 I）。这种高反应性物质在 3D 卤化铅框架中得以稳定存在，并且其尺寸小到足以作为有机阳离子促进半导体有机-无机材料的形成。
