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用于薄膜封装的FCVA沉积AlO/MgO复合薄膜的研究

A Study of AlO/MgO Composite Films Deposited by FCVA for Thin-Film Encapsulation.

作者信息

Yuan Heng, Zhang Yifan, Li Qian, Yan Weiqing, Zhang Xu, Ouyang Xiao, Ouyang Xiaoping, Chen Lin, Liao Bin

机构信息

College of Nuclear Science and Technology, Beijing Normal University, Beijing 100875, China.

Advanced Institute of Natural Sciences, Beijing Normal University at Zhuhai, Zhuhai 519087, China.

出版信息

Materials (Basel). 2023 Feb 27;16(5):1955. doi: 10.3390/ma16051955.

Abstract

AlO and MgO composite (AlO/MgO) films were rapidly deposited at low temperatures using filtered cathode vacuum arc (FCVA) technology, aiming to achieve good barrier properties for flexible organic light emitting diodes (OLED) thin-film encapsulation (TFE). As the thickness of the MgO layer decreases, the degree of crystallinity decreases gradually. The 3:2 AlO:MgO layer alternation type has the best water vapor shielding performance, and the water vapor transmittance (WVTR) is 3.26 × 10 g·m·day at 85 °C and 85% R.H, which is about 1/3 of that of a single layer of AlO film. Under the action of ion deposition, too many layers will cause internal defects in the film, resulting in decreased shielding ability. The surface roughness of the composite film is very low, which is about 0.3-0.5 nm depending on its structure. In addition, the visible light transmittance of the composite film is lower than that of a single film and increases with the increase in the number of layers.

摘要

采用过滤阴极真空电弧(FCVA)技术在低温下快速沉积AlO和MgO复合(AlO/MgO)薄膜,旨在实现用于柔性有机发光二极管(OLED)薄膜封装(TFE)的良好阻隔性能。随着MgO层厚度的减小,结晶度逐渐降低。AlO:MgO层交替比为3:2时具有最佳的水蒸气屏蔽性能,在85℃、相对湿度85%的条件下,水蒸气透过率(WVTR)为3.26×10 g·m·day,约为单层AlO薄膜的1/3。在离子沉积作用下,过多的层数会导致薄膜内部出现缺陷,从而使屏蔽能力下降。复合薄膜的表面粗糙度非常低,根据其结构不同约为0.3 - 0.5 nm。此外,复合薄膜的可见光透过率低于单层薄膜,且随层数增加而增大。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0b35/10003942/8dff3fb6fdf1/materials-16-01955-g001.jpg

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