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开级配磨耗层沥青混凝土中磷尾矿粉的回收利用研究

Research on Recycling of Phosphorus Tailings Powder in Open-Graded Friction Course Asphalt Concrete.

作者信息

Xiao Yue, Ju Xinjiang, Li Chao, Wang Tianlei, Wu Rui

机构信息

State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan 430070, China.

Green Building Materials and Manufacturing Engineering Research Center of the Ministry of Education, Wuhan University of Technology, Wuhan 430070, China.

出版信息

Materials (Basel). 2023 Feb 28;16(5):2000. doi: 10.3390/ma16052000.

Abstract

The reuse in high-value materials is one of the important resource utilization approaches of phosphorus tailings. At present, a mature technical system has been formed on the reuse of phosphorus slag in building materials, and silicon fertilizers in the extraction of yellow phosphorus. But there is a lack of research on the high-value reuse of phosphorus tailings. In order to make safe and effective utilization of phosphorus tailing resources, this research concentrated on how to solve easy agglomeration and difficult dispersion of phosphorus tailing micro-powder, when it was recycled in road asphalt. In the experimental procedure, phosphorus tailing micro-powder is treated in two methods. One method is to directly add it with different contents in asphalt to form a mortar. Dynamic shear tests were used to explore the effect of phosphorus tailing micro-powder on the high-temperature rheological properties of asphalt influence mechanism of material service behavior. The other method is to replace the mineral powder in asphalt mixture. The effect of phosphate tailing micro-powder on the water damage resistance in open-graded friction course (OGFC) asphalt mixtures was illustrated, based on the Marshall stability test and the freeze-thaw split test. The research results show that the performance indicators of the modified phosphorus tailing micro-powder meet the requirements for mineral powder in road engineering. Compared with standard OGFC asphalt mixtures, the residual stability of immersion and freeze-thaw splitting strength were improved when replace the mineral powder. The residual stability of immersion increased from 84.70% to 88.31%, and freeze-thaw splitting strength increased from 79.07% to 82.61%. The results indicate that phosphate tailing micro-powder has a certain positive effect on the water damage resistance. These performance improvements can be attributed to the larger specific surface area for phosphate tailing micro-powder than ordinary mineral powder, which can effectively adsorb asphalt and form structural asphalt. The research results are expected to support the large-scale reuse of phosphorus tailing powder in road engineering.

摘要

磷尾矿中高价值材料的再利用是磷尾矿资源利用的重要途径之一。目前,磷渣在建筑材料中的再利用以及黄磷提取中硅肥的生产已形成成熟的技术体系。但对于磷尾矿的高价值再利用研究较少。为了安全有效地利用磷尾矿资源,本研究聚焦于解决磷尾矿微粉在道路沥青中回收利用时易团聚、难分散的问题。在实验过程中,对磷尾矿微粉采用了两种处理方法。一种方法是在沥青中直接添加不同含量的磷尾矿微粉形成胶浆,采用动态剪切试验探究磷尾矿微粉对沥青高温流变性能的影响及材料服役行为的作用机制。另一种方法是替代沥青混合料中的矿粉,基于马歇尔稳定度试验和冻融劈裂试验,阐述了磷尾矿微粉对开级配磨耗层(OGFC)沥青混合料抗水损害性能的影响。研究结果表明,改性磷尾矿微粉的性能指标满足道路工程中矿粉的要求。与标准OGFC沥青混合料相比,替代矿粉后,其浸水残留稳定度和冻融劈裂强度均有所提高。浸水残留稳定度从84.70%提高到88.31%,冻融劈裂强度从79.07%提高到82.61%。结果表明,磷尾矿微粉对沥青混合料抗水损害性能有一定的积极作用。这些性能的提升可归因于磷尾矿微粉比普通矿粉具有更大的比表面积,能够有效吸附沥青并形成结构沥青。研究结果有望为磷尾矿粉在道路工程中的大规模再利用提供支撑。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/835c/10004336/548cd36a02f8/materials-16-02000-g001.jpg

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