铜催化不饱和分子的硼化官能化的最新进展。
Updated Progress of the Copper-Catalyzed Borylative Functionalization of Unsaturated Molecules.
机构信息
School of Materials Science and Engineering, PCFM Lab, Sun Yat-sen University, Guangzhou 510275, China.
School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, China.
出版信息
Molecules. 2023 Feb 28;28(5):2252. doi: 10.3390/molecules28052252.
Borylation has become a powerful method to synthesize organoboranes as versatile building blocks in organic synthesis, medicinal chemistry, and materials science. Copper-promoted borylation reactions are extremely attractive due to the low cost and non-toxicity of the copper catalyst, mild reaction conditions, good functional group tolerance, and convenience in chiral induction. In this review, we mainly updated recent advances (from 2020 to 2022) in the synthetic transformations in C=C/C≡C multiple bonds, and C=E multiple bonds mediated by copper boryl systems.
硼化已成为一种强大的方法，用于合成有机合成、药物化学和材料科学中多功能的有机硼化合物。由于铜催化剂成本低、毒性低、反应条件温和、对官能团的容忍度好以及手性诱导方便，铜促进的硼化反应极具吸引力。在这篇综述中，我们主要更新了（从 2020 年到 2022 年）铜硼体系介导的 C=C/C≡C 多重键和 C=E 多重键的合成转化的最新进展。
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