Zhang Qiang, Zou Xiao, Zhang Ningqi, Liu Bo
Shaanxi Key Laboratory of Catalysis, School of Chemistry and Environmental Science, Shaanxi University of Technology Han zhong 723001 P. R. China
RSC Adv. 2023 Mar 10;13(12):8043-8048. doi: 10.1039/d3ra00836c. eCollection 2023 Mar 8.
A novel cobalt-catalyzed protocol for the synthesis of carbinol derivatives and benzil derivatives has been developed. In the presence of CoI as the catalyst and tmphen (3,4,7,8-tetramethyl-1,10-phenanthroline) as the ligand, the corresponding arylated products were obtained from the addition of aryltrimethylgermanes to aromatic aldehydes and arylglyoxals in moderate to excellent yields under air atmosphere.
已开发出一种用于合成甲醇衍生物和联苯甲酰衍生物的新型钴催化方法。在碘化钴作为催化剂和tmphen（3,4,7,8-四甲基-1,10-菲咯啉）作为配体的存在下，在空气气氛中，通过芳基三甲基锗烷与芳香醛和芳基乙二醛的加成反应，以中等至优异的产率得到相应的芳基化产物。
