醋酸铜（II）催化芳基硼酸与芳香醛的加成反应。
Copper(II) acetate-catalyzed addition of arylboronic acids to aromatic aldehydes.
作者信息
Zheng Hanmei, Zhang Qiang, Chen Jiuxi, Liu Miaochang, Cheng Shuanghua, Ding Jinchang, Wu Huayue, Su Weike
机构信息
College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325027, PR China.
出版信息
J Org Chem. 2009 Jan 16;74(2):943-5. doi: 10.1021/jo802225j.
PMID:19067580
Abstract
A novel copper-catalyzed protocol for the synthesis of carbinol derivatives has been developed. In the presence of copper(II) acetate and dppf, carbinol derivatives were prepared by the addition of arylboronic acids to aromatic aldehydes in good to excellent yields. Moreover, the rigorous exclusion of air or moisture is not required in these transformations.
摘要
已开发出一种用于合成甲醇衍生物的新型铜催化方法。在乙酸铜和二(二苯基膦基)二茂铁存在下，通过将芳基硼酸加成到芳香醛中来制备甲醇衍生物，产率良好至优异。此外，这些转化过程中不需要严格排除空气或水分。
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