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基于等离子体相变材料 InSbTe 的宽带双曲热超表面。

Broadband hyperbolic thermal metasurfaces based on the plasmonic phase-change material InSbTe.

机构信息

Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China.

Optics Valley Laboratory, Hubei 430074, China.

出版信息

Nanoscale. 2023 Mar 30;15(13):6306-6312. doi: 10.1039/d2nr07133a.

Abstract

Thermal radiation modulation facilitated by phase change materials (PCMs) needs a large thermal radiation contrast in broadband as well as in a non-volatile phase transition, which are only partially satisfied by conventional PCMs. In contrast, the emerging plasmonic PCM InSbTe (IST) that undergoes a non-volatile dielectric-to-metal phase transition during crystallization offers a fitting solution. Here, we have prepared IST-based hyperbolic thermal metasurfaces and demonstrated their capabilities to modulate thermal radiation. By laser-printing crystalline IST gratings with different fill factors on amorphous IST films, we have achieved multilevel, large-range, and polarization-dependent control of the emissivity modulation (0.07 for the crystalline phase and 0.73 for the amorphous phase) over a broad bandwidth (8-14 μm). With the convenient direct laser writing technique that supports large-scale surface patterning, we have also demonstrated promising applications of thermal anti-counterfeiting with hyperbolic thermal metasurfaces.

摘要

相变材料(PCM)的热辐射调控需要在宽带和非易失性相变中具有大的热辐射对比度,这仅部分满足于传统的 PCM。相比之下,新兴的等离子体 PCM InSbTe(IST)在结晶过程中经历非易失性介电到金属的相变,提供了一个合适的解决方案。在这里,我们制备了基于 IST 的双曲热超表面,并展示了它们调制热辐射的能力。通过在非晶 IST 薄膜上用不同填充因子的激光打印结晶 IST 光栅,我们实现了在宽频带(8-14μm)上对发射率调制的多级、大范围和偏振相关控制(结晶相为 0.07,非晶相为 0.73)。通过支持大规模表面图案化的便捷直接激光写入技术,我们还展示了具有双曲热超表面的热防伪的有前途的应用。

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