Wuhan National Laboratory for Optoelectronics, School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074, China.
Optics Valley Laboratory, Hubei 430074, China.
Nanoscale. 2023 Mar 30;15(13):6306-6312. doi: 10.1039/d2nr07133a.
Thermal radiation modulation facilitated by phase change materials (PCMs) needs a large thermal radiation contrast in broadband as well as in a non-volatile phase transition, which are only partially satisfied by conventional PCMs. In contrast, the emerging plasmonic PCM InSbTe (IST) that undergoes a non-volatile dielectric-to-metal phase transition during crystallization offers a fitting solution. Here, we have prepared IST-based hyperbolic thermal metasurfaces and demonstrated their capabilities to modulate thermal radiation. By laser-printing crystalline IST gratings with different fill factors on amorphous IST films, we have achieved multilevel, large-range, and polarization-dependent control of the emissivity modulation (0.07 for the crystalline phase and 0.73 for the amorphous phase) over a broad bandwidth (8-14 μm). With the convenient direct laser writing technique that supports large-scale surface patterning, we have also demonstrated promising applications of thermal anti-counterfeiting with hyperbolic thermal metasurfaces.
相变材料(PCM)的热辐射调控需要在宽带和非易失性相变中具有大的热辐射对比度,这仅部分满足于传统的 PCM。相比之下,新兴的等离子体 PCM InSbTe(IST)在结晶过程中经历非易失性介电到金属的相变,提供了一个合适的解决方案。在这里,我们制备了基于 IST 的双曲热超表面,并展示了它们调制热辐射的能力。通过在非晶 IST 薄膜上用不同填充因子的激光打印结晶 IST 光栅,我们实现了在宽频带(8-14μm)上对发射率调制的多级、大范围和偏振相关控制(结晶相为 0.07,非晶相为 0.73)。通过支持大规模表面图案化的便捷直接激光写入技术,我们还展示了具有双曲热超表面的热防伪的有前途的应用。