Baranov Oleg, Bazaka Kateryna, Belmonte Thierry, Riccardi Claudia, Roman H Eduardo, Mohandas Mandhakini, Xu Shuyan, Cvelbar Uroš, Levchenko Igor
Department of Theoretical Mechanics, Engineering and Robomechanical Systems, National Aerospace University, Kharkiv 61070, Ukraine.
Department of Gaseous Electronics, Jozef Stefan Institute, Ljubljana 1000, Slovenia.
Nanoscale Horiz. 2023 May 2;8(5):568-602. doi: 10.1039/d2nh00546h.
Low-dimensional copper oxide nanostructures are very promising building blocks for various functional materials targeting high-demanded applications, including energy harvesting and transformation systems, sensing and catalysis. Featuring a very high surface-to-volume ratio and high chemical reactivity, these materials have attracted wide interest from researchers. Currently, extensive research on the fabrication and applications of copper oxide nanostructures ensures the fast progression of this technology. In this article we briefly outline some of the most recent, mostly within the past two years, innovations in well-established fabrication technologies, including oxygen plasma-based methods, self-assembly and electric-field assisted growth, electrospinning and thermal oxidation approaches. Recent progress in several key types of leading-edge applications of CuO nanostructures, mostly for energy, sensing and catalysis, is also reviewed. Besides, we briefly outline and stress novel insights into the effect of various process parameters on the growth of low-dimensional copper oxide nanostructures, such as the heating rate, oxygen flow, and roughness of the substrates. These insights play a key role in establishing links between the structure, properties and performance of the nanomaterials, as well as finding the cost-and-benefit balance for techniques that are capable of fabricating low-dimensional CuO with the desired properties and facilitating their integration into more intricate material architectures and devices without the loss of original properties and function.
低维氧化铜纳米结构是用于各种针对高要求应用的功能材料的非常有前景的构建块,这些应用包括能量收集和转换系统、传感和催化。这些材料具有非常高的表面体积比和高化学反应活性,吸引了研究人员的广泛关注。目前,对氧化铜纳米结构的制备和应用的广泛研究确保了该技术的快速发展。在本文中,我们简要概述了一些最新的创新,主要是过去两年内,在成熟的制备技术方面的创新,包括基于氧等离子体的方法、自组装和电场辅助生长、静电纺丝和热氧化方法。还综述了CuO纳米结构在几个关键类型的前沿应用中的最新进展,主要用于能量、传感和催化。此外,我们简要概述并强调了关于各种工艺参数对低维氧化铜纳米结构生长的影响的新见解,例如加热速率、氧气流量和衬底的粗糙度。这些见解在建立纳米材料的结构、性质和性能之间的联系,以及为能够制备具有所需性质的低维CuO并促进其集成到更复杂的材料结构和器件中而不损失原始性质和功能的技术找到成本效益平衡方面起着关键作用。