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过渡金属硫化物与静电纺丝相结合:多功能合成、独特性质及潜在应用

Transition metal sulfides meet electrospinning: versatile synthesis, distinct properties and prospective applications.

作者信息

Zhu Wendong, Cheng Ya, Wang Ce, Pinna Nicola, Lu Xiaofeng

机构信息

Alan G. MacDiarmid Institute, College of Chemistry, Jilin University, Changchun, 130012, P. R. China.

Institut für Chemie and IRIS Adlershof, Humboldt-Universität zu Berlin, Brook-Taylor-Straße 2, 12489 Berlin, Germany.

出版信息

Nanoscale. 2021 May 27;13(20):9112-9146. doi: 10.1039/d1nr01070k.

Abstract

One-dimensional (1D) electrospun nanomaterials have attracted significant attention due to their unique structures and outstanding chemical and physical properties such as large specific surface area, distinct electronic and mass transport, and mechanical flexibility. Over the past years, the integration of metal sulfides with electrospun nanomaterials has emerged as an exciting research topic owing to the synergistic effects between the two components, leading to novel and interesting properties in energy, optics and catalysis research fields for example. In this review, we focus on the recent development of the preparation of electrospun nanomaterials integrated with functional metal sulfides with distinct nanostructures. These functional materials have been prepared via two efficient strategies, namely direct electrospinning and post-synthesis modification of electrospun nanomaterials. In this review, we systematically present the chemical and physical properties of the electrospun nanomaterials integrated with metal sulfides and their application in electronic and optoelectronic devices, sensing, catalysis, energy conversion and storage, thermal shielding, adsorption and separation, and biomedical technology. Additionally, challenges and further research opportunities in the preparation and application of these novel functional materials are also discussed.

摘要

一维(1D)电纺纳米材料因其独特的结构以及诸如大比表面积、独特的电子和质量传输特性、机械柔韧性等优异的化学和物理性质而备受关注。在过去几年中,金属硫化物与电纺纳米材料的结合已成为一个令人兴奋的研究课题,这是由于这两种组分之间的协同效应,例如在能源、光学和催化研究领域产生了新颖有趣的性质。在本综述中,我们重点关注与具有独特纳米结构的功能性金属硫化物相结合的电纺纳米材料制备的最新进展。这些功能材料是通过两种有效策略制备的,即直接电纺和电纺纳米材料的合成后修饰。在本综述中,我们系统地介绍了与金属硫化物相结合的电纺纳米材料的化学和物理性质及其在电子和光电器件、传感、催化、能量转换与存储、热屏蔽、吸附与分离以及生物医学技术中的应用。此外,还讨论了这些新型功能材料在制备和应用方面的挑战及进一步的研究机会。

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