Construction of Heterometallic Coordination Nanosheets Comprising Both Inert and Labile Metal Ions Together via Metalloligand Approach.

Construction of coordination nanosheets (CONASHs) containing both inert and labile metal ions together is fundamentally significant but remains synthetically unachievable until now and difficult to realize via conventional synthetic approach of CONASHs due to variable complexation conditions between heterometal ions and organic ligands. Here, we demonstrate a strategy to harness both inert and labile metal ions together into a CONASHs structure by introducing the concept of a metalloligand. Metalloligands comprising inert metal ion (Os/Ru) and free coordinating sites are designed and synthesized and can be further used as coordinating ligand to bind labile heterometal ion (Fe) for building of heterometallic CONASHs (HMCONASHs). Following this, two HMCONASHs containing homoleptic heterometallic complexes are constructed that show broad absorption and electrochemical window with reversible dual redox activity. Further, HMCONASH films exhibit multicolor electrochromism at different voltages, indicating their potential for various applications. This synthetic approach may open a window to create CONASHs with diverse structures and functions that are hard to achieve via a traditional synthetic approach.