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开发一种ZnOS+C复合材料作为潜在吸附剂用于从实际废水中有效去除固绿染料。

Development of a ZnOS+C Composite as a Potential Adsorbent for the Effective Removal of Fast Green Dye from Real Wastewater.

作者信息

Pramanik Biplob Kumar, Gupta Harshit, Kumar Shrawan, Tawale Jai Shankar, Shah Kalpit, Varathan Ezhilselvi, Singh Nahar

机构信息

BND Division, CSIR-National Physical Laboratory, Dr. K.S. Krishnan Marg, New Delhi 110012, India.

Academy of Scientific and Innovative Research (AcSIR), Ghaziabad 201002, India.

出版信息

ACS Omega. 2023 Mar 3;8(10):9230-9238. doi: 10.1021/acsomega.2c06873. eCollection 2023 Mar 14.

Abstract

Wastewater treatment is becoming increasingly important due to the potential shortage of pure drinking water in many parts of the world. Adsorption offers a potential technique for the uptake of contaminants and wastewater purification. In the last two decades, several efforts have been made to remove fast green (FG) dye from wastewater via different adsorbent materials. However, adsorption capacity shown by these adsorbents is low and time-consuming. Herein, we have synthesized for the first time a new powdered adsorbent ZnOS+C, modified zinc peroxide with sulfur and activated carbon to effectively remove FG dye from wastewater. Results of batch adsorption experiments have suggested that ZnOS+C has the maximum adsorption potential of 238.28 mg/g for FG dye within 120 min of adsorption equilibrium for a wide range of pH ranging from 2 to 10 pH. The adsorption process conforms to the Freundlich isotherm model, suggesting a multilayered adsorption process on the outer surface of ZnOS+C. The adsorption kinetics study indicates that the kinetics of the reaction are the intraparticle diffusion model. Briefly, this study shows proof of the application of ZnOS+C powder as a new eco-friendly adsorbent with extremely high efficiency and high surface area for removing FG dye.

摘要

由于世界许多地区潜在的纯净饮用水短缺,废水处理变得越来越重要。吸附为污染物的吸收和废水净化提供了一种潜在技术。在过去二十年中,人们通过不同的吸附材料努力从废水中去除固绿(FG)染料。然而,这些吸附剂显示出的吸附容量较低且耗时。在此,我们首次合成了一种新型粉末吸附剂ZnOS+C,即经硫和活性炭改性的过氧化锌,以有效去除废水中的FG染料。批量吸附实验结果表明,在pH值范围为2至10的广泛条件下,ZnOS+C在120分钟吸附平衡时对FG染料的最大吸附潜力为238.28 mg/g。吸附过程符合Freundlich等温线模型,表明在ZnOS+C外表面发生多层吸附过程。吸附动力学研究表明,反应动力学符合颗粒内扩散模型。简而言之,本研究证明了ZnOS+C粉末作为一种新型环保吸附剂,在去除FG染料方面具有极高的效率和高表面积。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3689/10018503/fbf50040b76e/ao2c06873_0010.jpg

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Recent advances for dyes removal using novel adsorbents: A review.新型吸附剂在染料去除方面的最新进展:综述。
Environ Pollut. 2019 Sep;252(Pt A):352-365. doi: 10.1016/j.envpol.2019.05.072. Epub 2019 May 16.

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