Potential risks, source apportionment, and health risk assessment of dissolved heavy metals in Zhoushan fishing ground, China.

Dissolved heavy metal pollution in the ocean is one of the most severe environmental concerns; however, the potential sources of heavy metals and the resulting health risks are not fully understood. To explore the distribution characteristics, source apportionment, and health risks of dissolved heavy metals (As, Cd, Cu, Hg, Pb, and Zn) in the Zhoushan fishing ground, this study analyzed heavy metals in surface seawater during the wet and dry seasons. The concentrations of heavy metals varied greatly between seasons, and the mean concentration in the wet season was generally higher than that in the dry season. A positive matrix factorization model coupled with correlation analysis was applied to identify promising sources of heavy metals. Four potential sources (agricultural, industrial, traffic, atmospheric deposition, and natural sources) were identified as the determinants of the accumulation of heavy metals. The health risk assessment results revealed that non-carcinogenic risk (NCR) for adults and children were acceptable (HI < 1), and carcinogenic risk (CR) were at a low level (1 × 10 < TCR ≤ 1 × 10). The source-oriented risk assessment indicated that industrial and traffic sources were the main sources of pollution, contributing 40.7 % of NCR and 27.4 % of CR, respectively. This study proposes forming reasonable, effective policies to control industrial pollution and improve the ecological environment of Zhoushan fishing grounds.