Xu Shengqing, Wu Weihua, Gu Han, Zhou Xiaochen, Zhu Xiaoqin, Zhai Jiwei, Song Sannian, Song Zhitang
School of Mathematics and Physics, Jiangsu University of Technology, Changzhou 213001, People's Republic of China.
Shanghai Key Laboratory for R&D and Application of Metallic Functional Materials, School of Materials Science & Engineering, Tongji University, Shanghai 201804, People's Republic of China.
Nanotechnology. 2023 Apr 12;34(26). doi: 10.1088/1361-6528/acc80f.
The effects of yttrium dopants on the phase change behavior and microstructure of SnSbfilms have been systematically investigated. The yttrium-doped SnSbfilm has the higher phase transition temperature, ten year data retention ability and crystallization activation energy, which represent a great improvement in thermal stability and data retention. X-ray diffraction, transmission electron microscopy and x-ray photoelectron spectroscopy reveal that the amorphous Sn and Y components restrict the grain growth and decrease the grain size. Raman mode typically associated with Sb is altered when the substance crystallized. Atomic force microscopy results show that the surface morphology of the doped films becomes smoother. T-shaped phase change storage cells based on yttrium-doped SnSbfilms exhibit the lower power consumption. The results demonstrate that the crystallization characteristics of SnSbfilm can be tuned and optimized through the yttrium dopant for the excellent performances of phase change memory.