Tong Xin, Yang Zhuo, Zhang Jiali, Li Wenbing, Liu Bo, Chen Chang
School of Microelectronics, Shanghai University, Shanghai 201800, China.
Shanghai Industrial Technology Research Institute, Shanghai 201800, China.
Materials (Basel). 2023 Mar 14;16(6):2316. doi: 10.3390/ma16062316.
The color reflector with multiple-layer thin film scheme has attracted much attention because of the potential for massive production by wafer-scale deposition and the possibility to integrate with photonics (semiconductor) devices. Here, an angle-insensitive green reflector with a simple multilayer dielectric thin film structure was reported, with predicted chromatic coordinates based on CIE 1931 standard. The SiN/SiO multilayer thin film stack, including a special silicon-rich nitride material with ultrahigh refractive index, was grown alternatively by an inductively coupled plasma chemical vapor deposition (ICPCVD) system at a low stage temperature of 80 °C. The green reflector showed a maximum reflectivity of 73% around 561 nm with a full width at half maximum (FWHM) of 87 nm in the visible wavelength range, which contributed significantly to its color appearance. The measurement by an angle-resolved spectrometer under the illumination of p/s-polarized light wave with a variable angle of incidence indicated that the reflectance spectrum blue-shifted slightly with the increasing of incident angle such that the green color could be kept.
具有多层薄膜结构的彩色反射器因有望通过晶圆级沉积进行大规模生产以及与光子学(半导体)器件集成的可能性而备受关注。在此,报道了一种具有简单多层介质薄膜结构的角度不敏感绿色反射器,并基于CIE 1931标准预测了色度坐标。通过电感耦合等离子体化学气相沉积(ICPCVD)系统在80°C的低温下交替生长包括具有超高折射率的特殊富硅氮化物材料的SiN/SiO多层薄膜堆栈。该绿色反射器在可见光波长范围内561nm左右显示出73%的最大反射率,半高宽(FWHM)为87nm,这对其颜色外观有显著贡献。在具有可变入射角的p/s偏振光波照射下通过角度分辨光谱仪进行的测量表明,反射光谱随着入射角的增加而略有蓝移,从而可以保持绿色。