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基于碱性氧气转炉炉渣和磨细粒化高炉矿渣的碱激发砂浆性能的试验与统计研究

Experimental and Statistical Study on the Properties of Basic Oxygen Furnace Slag and Ground Granulated Blast Furnace Slag Based Alkali-Activated Mortar.

作者信息

Özkan Hakan, Miyan Nausad, Kabay Nihat, Omur Tarik

机构信息

Oyak Cement Concrete Paper Group/Betâo Liz SA, 1099-020 Lisbon, Portugal.

Department of Civil Engineering, Yildiz Technical University, Istanbul 34220, Turkey.

出版信息

Materials (Basel). 2023 Mar 15;16(6):2357. doi: 10.3390/ma16062357.

Abstract

Basic oxygen furnace slag (BOFS) is a waste material generated during the steelmaking process and has the potential to harm both the environment and living organisms when disposed of in a landfill. However, the cementitious properties of BOFS might help in utilizing this waste as an alternative material in alkali-activated systems. Therefore, in this study, BOFS and blast furnace slag were activated with varying dosages of NaOH, and the fresh, physical, mechanical, and microstructural properties were determined along with statistical analysis to reach the optimal mix design. The test results showed that an increase in BOFS content decreased compressive and flexural strengths, whereas it slightly increased the water absorption and permeable pores of the tested mortar samples. On the contrary, the increase in NaOH molarity resulted in a denser microstructure, reduced water absorption and permeable pores, and improved mechanical properties. Statistically significant relationships were obtained through response surface methodology with optimal mix proportions, namely, (i) 24.61% BOFS and 7.74 M and (ii) 20.00% BOFS and 8.90 M, which maximize the BOFS content with lower molarity and improve the mechanical properties with lower water absorption and porosity, respectively. The proposed methodology maximizes the utilization of waste BOFS in alkali-activated systems and may promote environmental and economic benefits.

摘要

碱性氧气转炉炉渣(BOFS)是炼钢过程中产生的一种废料,当被填埋处理时,有可能对环境和生物造成危害。然而,BOFS的胶凝特性可能有助于将这种废料用作碱激活体系中的替代材料。因此,在本研究中,用不同剂量的NaOH对BOFS和高炉矿渣进行激活,并测定其新拌、物理、力学和微观结构性能,同时进行统计分析以得出最佳配合比设计。试验结果表明,BOFS含量的增加会降低抗压强度和抗折强度,而会略微增加所测试砂浆样品的吸水率和连通孔隙率。相反,NaOH摩尔浓度的增加会导致微观结构更致密,吸水率和连通孔隙率降低,力学性能得到改善。通过响应面法获得了具有最佳配合比的统计学显著关系,即:(i)24.61%的BOFS和7.74 M以及(ii)20.00%的BOFS和8.90 M,它们分别在较低摩尔浓度下使BOFS含量最大化,并在较低吸水率和孔隙率的情况下改善力学性能。所提出的方法在碱激活体系中最大限度地利用了废弃的BOFS,并可能带来环境和经济效益。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2ca2/10057091/377c161e2ff2/materials-16-02357-g001.jpg

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