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提高 1-cm 全钙钛矿串联太阳能电池的界面质量。

Improving interface quality for 1-cm all-perovskite tandem solar cells.

机构信息

College of Materials Science and Engineering & Institute of New Energy and Low-Carbon Technology & Engineering Research Center of Alternative Energy Materials and Devices, Ministry of Education, Sichuan University, Chengdu, China.

Institute of Flexible Electronics (IFE, Future Technologies), Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM), Xiamen University, Xiamen, China.

出版信息

Nature. 2023 Jun;618(7963):80-86. doi: 10.1038/s41586-023-05992-y. Epub 2023 Mar 29.

Abstract

All-perovskite tandem solar cells provide high power conversion efficiency at a low cost. Rapid efficiency improvement in small-area (<0.1 cm) tandem solar cells has been primarily driven by advances in low-bandgap (approximately 1.25 eV) perovskite bottom subcells. However, unsolved issues remain for wide-bandgap (> 1.75 eV) perovskite top subcells, which at present have large voltage and fill factor losses, particularly for large-area (>1 cm) tandem solar cells. Here we develop a self-assembled monolayer of (4-(7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid as a hole-selective layer for wide-bandgap perovskite solar cells, which facilitates subsequent growth of high-quality wide-bandgap perovskite over a large area with suppressed interfacial non-radiative recombination, enabling efficient hole extraction. By integrating (4-(7H-dibenzo[c,g]carbazol-7-yl)butyl)phosphonic acid in devices, we demonstrate a high open-circuit voltage (V) of 1.31 V in a 1.77-eV perovskite solar cell, corresponding to a very low V deficit of 0.46 V (with respect to the bandgap). With these wide-bandgap perovskite subcells, we report 27.0% (26.4% certified stabilized) monolithic all-perovskite tandem solar cells with an aperture area of 1.044 cm. The certified tandem cell shows an outstanding combination of a high V of 2.12 V and a fill factor of 82.6%. Our demonstration of the large-area tandem solar cells with high certified efficiency is a key step towards scaling up all-perovskite tandem photovoltaic technology.

摘要

全钙钛矿串联太阳能电池以低成本提供了高的功率转换效率。在小面积(<0.1 平方厘米)串联太阳能电池中,效率的快速提高主要得益于低带隙(约 1.25 电子伏特)钙钛矿底子电池的进步。然而,宽带隙(>1.75 电子伏特)钙钛矿顶子电池仍存在未解决的问题,目前这些问题导致大电压和填充因子损失,特别是对于大面积(>1 平方厘米)串联太阳能电池。在这里,我们开发了一种(4-(7H-二苯并[c,g]咔唑-7-基)丁基)膦酸的自组装单层作为宽带隙钙钛矿太阳能电池的空穴选择层,这促进了高质量宽带隙钙钛矿在大面积上的后续生长,同时抑制了界面非辐射复合,从而实现了高效的空穴提取。通过在器件中整合(4-(7H-二苯并[c,g]咔唑-7-基)丁基)膦酸,我们在 1.77 电子伏特的钙钛矿太阳能电池中实现了 1.31 伏特的高开路电压(V),这对应于非常低的 0.46 伏特的 V 亏损(相对于带隙)。有了这些宽带隙钙钛矿子电池,我们报告了具有 1.044 平方厘米有效面积的 27.0%(26.4%经认证稳定)单片全钙钛矿串联太阳能电池。经认证的串联电池表现出 2.12 伏特的高 V 和 82.6%的填充因子的出色组合。我们对具有高经认证效率的大面积串联太阳能电池的演示是向全钙钛矿串联光伏技术扩展的关键步骤。

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