Department of Chemistry "Ugo Schiff", University of Florence, Florence, Italy; Institute of Polar Sciences, ISP-CNR, Venice-Mestre, Italy.
Department of Chemistry "Ugo Schiff", University of Florence, Florence, Italy; Institute of Polar Sciences, ISP-CNR, Venice-Mestre, Italy.
Chemosphere. 2023 Jul;329:138674. doi: 10.1016/j.chemosphere.2023.138674. Epub 2023 Apr 11.
Starting from 1952 C.E. more than 540 atmospheric nuclear weapons tests (NWT) were conducted in different locations of the Earth. This lead to the injection of about 2.8 t of Pu in the environment, roughly corresponding to a total Pu radioactivity of 6.5 PBq. A semiquantitative ICP-MS method was used to measure this isotope in an ice core drilled in Dome C (East Antarctica). The age scale for the ice core studied in this work was built by searching for well-known volcanic signatures and synchronising these sulfate spikes with established ice core chronologies. The reconstructed plutonium deposition history was compared with previously published NWT records, pointing out an overall agreement. The geographical location of the tests was found to be an important parameter strongly affecting the concentration of Pu on the Antarctic ice sheet. Despite the low yield of the tests conducted in the 1970s, we highlight their important role in the deposition of radioactivity in Antarctica due to the relative closeness of the testing sites.
自公元 1952 年以来,全球各地共进行了超过 540 次大气核武器试验(NWT)。这导致约 2.8 吨 Pu 被注入环境中,总 Pu 放射性约为 6.5 PBq。本研究采用半定量 ICP-MS 方法测量了在南极 Dome C 钻取的冰芯中这一同位素的含量。这项研究中所使用的冰芯的年龄尺度是通过寻找已知的火山特征并将这些硫酸盐峰值与已建立的冰芯年表同步来构建的。重建的钚沉积历史与之前发表的 NWT 记录进行了比较,结果表明总体上是一致的。测试的地理位置是一个重要的参数,它强烈影响着南极冰盖中 Pu 的浓度。尽管 20 世纪 70 年代进行的试验的产量较低,但由于测试地点相对较近,我们强调了它们在南极洲放射性沉积方面的重要作用。