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氧化石墨烯对电化学生长氧化镍超级电容器性能的增强作用

Enhancement of Supercapacitor Performance of Electrochemically Grown Nickel Oxide by Graphene Oxide.

作者信息

BinSabt Mohammad H, Galal Ahmed, Abdel Nazeer Ahmed

机构信息

Chemistry Department, Faculty of Science, University of Kuwait, P.O. Box 5969, Safat 13060, Kuwait.

出版信息

Materials (Basel). 2023 Apr 13;16(8):3068. doi: 10.3390/ma16083068.

Abstract

β-Ni(OH) and β-Ni(OH)/graphene oxide (GO) were prepared on an Ni foil electrode using the electrochemical cyclic voltammetry formed in 0.5 M KOH solution. Several surface analyses such as XPS, XRD, and Raman spectroscopies were used to confirm the chemical structure of the prepared materials. The morphologies were determined using SEM and AFM. The addition of the graphene oxide layer showed a remarkable increase in the specific capacitance of the hybrid. Through the measurements, the specific capacitance values were 280 F g and 110 F g after and before adding 4 layers of GO, respectively. The supercapacitor displays high stability until 500 cycles are charged and discharged almost without a loss in its capacitance values.

摘要

采用电化学循环伏安法在0.5 M KOH溶液中,在镍箔电极上制备了β-Ni(OH)和β- Ni(OH)/氧化石墨烯(GO)。利用X射线光电子能谱(XPS)、X射线衍射(XRD)和拉曼光谱等几种表面分析方法来确定所制备材料的化学结构。通过扫描电子显微镜(SEM)和原子力显微镜(AFM)确定其形貌。氧化石墨烯层的加入显著提高了复合材料的比电容。通过测量,在添加4层GO前后,比电容值分别为280 F/g和110 F/g。该超级电容器在500次充放电循环中显示出高稳定性,其电容值几乎没有损失。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0d93/10143060/d8abb64a03ee/materials-16-03068-g002.jpg

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