Kavitha Rajan, Latifah Omar, Ahmed Osumanu Haruna, Charles Primus Walter, Susilawati Kasim
Department of Crop Science, Faculty of Agricultural Science and Forestry, Universiti Putra Malaysia, Bintulu Sarawak Campus, Bintulu 97008, Malaysia.
Institute of Ecosystem Science Borneo, Universiti Putra Malaysia, Bintulu Sarawak Campus, Bintulu 97008, Malaysia.
Polymers (Basel). 2023 Apr 13;15(8):1863. doi: 10.3390/polym15081863.
Increases in food production to meet global food requirements lead to an increase in the demand for nitrogen (N) fertilizers, especially urea, for soil productivity, crop yield, and food security improvement. To achieve a high yield of food crops, the excessive use of urea has resulted in low urea-N use efficiency and environmental pollution. One promising alternative to increase urea-N use efficiency, improve soil N availability, and lessen the potential environmental effects of the excessive use of urea is to encapsulate urea granules with appropriate coating materials to synchronize the N release with crop assimilation. Chemical additives, such as sulfur-based coatings, mineral-based coatings, and several polymers with different action principles, have been explored and used for coating the urea granule. However, their high material cost, limited resources, and adverse effects on the soil ecosystem limit the widespread application of urea coated with these materials. This paper documents a review of issues related to the materials used for urea coating and the potential of natural polymers, such as rejected sago starch, as a coating material for urea encapsulation. The aim of the review is to unravel an understanding of the potential of rejected sago starch as a coating material for the slow release of N from urea. Rejected sago starch from sago flour processing is a natural polymer that could be used to coat urea because the starch enables a gradual, water-driven mechanism of N release from the urea-polymer interface to the polymer-soil interface. The advantages of rejected sago starch for urea encapsulation over other polymers are that rejected sago starch is one of the most abundant polysaccharide polymers, the cheapest biopolymer, and is fully biodegradable, renewable, and environmentally friendly. This review provides information on the potential of rejected sago starch as a coating material, the advantages of using rejected sago starch as coating material over other polymer materials, a simple coating method, and the mechanisms of N release from urea coated with rejected sago starch.
为满足全球粮食需求而增加粮食产量,导致对氮肥(尤其是尿素)的需求增加,以提高土壤生产力、作物产量和粮食安全性。为实现粮食作物的高产,过量使用尿素导致尿素氮利用效率低下和环境污染。一种有望提高尿素氮利用效率、改善土壤氮有效性并减轻过量使用尿素潜在环境影响的替代方法是用合适的包膜材料包裹尿素颗粒,使氮素释放与作物吸收同步。化学添加剂,如硫基包膜材料、矿物基包膜材料以及几种作用原理不同的聚合物,已被研究并用于包裹尿素颗粒。然而,它们高昂的材料成本、有限的资源以及对土壤生态系统的不利影响限制了这些材料包膜尿素的广泛应用。本文综述了与尿素包膜材料相关的问题以及天然聚合物(如废弃西米淀粉)作为尿素包膜材料的潜力。综述的目的是阐明对废弃西米淀粉作为尿素氮缓释包膜材料潜力的理解。西米粉加工过程中产生的废弃西米淀粉是一种天然聚合物,可用于包裹尿素,因为这种淀粉能使氮从尿素 - 聚合物界面到聚合物 - 土壤界面通过水驱动实现逐步释放机制。废弃西米淀粉用于尿素包膜相对于其他聚合物的优势在于,废弃西米淀粉是最丰富的多糖聚合物之一,是最便宜的生物聚合物,并且完全可生物降解、可再生且环保。本综述提供了关于废弃西米淀粉作为包膜材料的潜力、使用废弃西米淀粉作为包膜材料相对于其他聚合物材料的优势、一种简单的包膜方法以及废弃西米淀粉包膜尿素的氮释放机制等信息。