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紫外线C辐射对3D打印丙烯腈-丁二烯-苯乙烯共聚物与聚碳酸酯聚合物的影响。

Effect of UV-C Radiation on 3D Printed ABS-PC Polymers.

作者信息

Amza Catalin Gheorghe, Zapciu Aurelian, Baciu Florin, Radu Constantin

机构信息

Faculty of Industrial Engineering and Robotics, University Politehnica of Bucharest, 060042 Bucharest, Romania.

出版信息

Polymers (Basel). 2023 Apr 21;15(8):1966. doi: 10.3390/polym15081966.

Abstract

During the initial stages of the COVID-19 pandemic, healthcare facilities experienced severe shortages of personal protective equipment (PPE) and other medical supplies. Employing 3D printing to rapidly fabricate functional parts and equipment was one of the emergency solutions used to tackle these shortages. Using ultraviolet light in the UV-C band (wavelengths of 200 nm to 280 nm) might prove useful in sterilizing 3D printed parts, enabling their reusability. Most polymers, however, degrade under UV-C radiation, so it becomes necessary to determine what 3D printing materials can withstand the conditions found during medical equipment sterilization with UV-C. This paper analyzes the effect of accelerated aging through prolonged exposure to UV-C on the mechanical properties of parts 3D printed from a polycarbonate and acrylonitrile butadiene styrene polymer (ABS-PC). Samples 3D printed using a material extrusion process (MEX) went through a 24-h UV-C exposure aging cycle and then were tested versus a control group for changes in tensile strength, compressive strength and some selected material creep characteristics. Testing showed minimal mechanical property degradation following the irradiation procedure, with tensile strength being statistically the same for irradiated parts as those in the control group. Irradiated parts showed small losses in stiffness (5.2%) and compressive strength (6.5%). Scanning electron microscopy (SEM) was employed in order to assess if any changes occurred in the material structure.

摘要

在新冠疫情初期,医疗机构面临个人防护装备(PPE)和其他医疗用品的严重短缺。利用3D打印快速制造功能部件和设备是应对这些短缺的应急解决方案之一。使用UV-C波段(波长200纳米至280纳米)的紫外线可能有助于对3D打印部件进行消毒,使其能够重复使用。然而,大多数聚合物在UV-C辐射下会降解,因此有必要确定哪些3D打印材料能够承受医疗设备UV-C消毒过程中的条件。本文分析了通过长时间暴露于UV-C进行加速老化对聚碳酸酯和丙烯腈丁二烯苯乙烯聚合物(ABS-PC)3D打印部件机械性能的影响。使用材料挤出工艺(MEX)3D打印的样品经过24小时的UV-C暴露老化循环,然后与对照组进行测试,以检测拉伸强度、抗压强度和一些选定的材料蠕变特性的变化。测试表明,辐照程序后机械性能降解最小,辐照部件的拉伸强度与对照组在统计学上相同。辐照部件的刚度(5.2%)和抗压强度(6.5%)略有损失。采用扫描电子显微镜(SEM)来评估材料结构是否发生任何变化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0246/10141134/c59f65762bdc/polymers-15-01966-g001.jpg

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