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老化后不同填充率和颜色的3D打印部件的力学性能和颜色变化研究

Investigation of Mechanical Properties and Color Changes of 3D-Printed Parts with Different Infill Ratios and Colors After Aging.

作者信息

Koçar Oğuz, Anaç Nergizhan, Baysal Erhan, Parmaksız Furkan, Akgül İrfan

机构信息

Department of Mechanical Engineering, Faculty of Engineering, Zonguldak Bülent Ecevit University, Zonguldak 67100, Türkiye.

Alaplı Vocational School, Zonguldak Bülent Ecevit University, Zonguldak 67850, Türkiye.

出版信息

Materials (Basel). 2024 Dec 3;17(23):5908. doi: 10.3390/ma17235908.

Abstract

Since their inception, plastics have become indispensable materials. However, plastics used for extended periods in industrial applications are prone to aging, which negatively impacts their material behavior and performance. To ensure the long-term usability of these materials, they must be tested in real-time, in-service environments to assess degradation. In practice, however, accelerated aging techniques are commonly employed to avoid time loss. Over time, various indicators of degradation in plastics emerge, such as changes in molecular weight, cracking, and mechanical properties like strain at break and impact strength. Among these, color deterioration or change is a critical factor that helps evaluate the service life of these materials. Considering the increasing use of plastics in 3D printing today, and the growing focus on strength over aesthetics in these applications, it is particularly useful to evaluate aging in plastics based on the relationship between color and strength. The wide application of 3D printing in various industries necessitates understanding material properties under aging conditions. This study examines the effects of aging on the mechanical behavior of polylactic acid (PLA) with three different colors (yellow, orange, and red) and three different infill ratios (20%, 60%, and 100%). The samples underwent an accelerated aging process of 432 h, which included 8 h of UV radiation, 15 min of water spraying, followed by 3 h and 45 min with the UV lamps turned off. Tensile tests, bending tests, hardness measurements, and color evaluations were conducted on the samples, linking the color changes after aging with the materials' mechanical properties. The results show that after aging, yellow samples with a 100% infill ratio exhibited a 6.9% increase in tensile strength (44.50 MPa to 47.58 MPa). Orange samples with a 100% infill ratio were less affected by aging, while red samples experienced a decrease in tensile strength across all infill ratios. Regarding bending force, increases were observed in the orange, yellow, and red samples by 10.37%, 25.05%, and 8.87%, respectively. This study underscores the importance of color selection when designing 3D-printed materials for long-term applications.

摘要

自问世以来,塑料已成为不可或缺的材料。然而,在工业应用中长时间使用的塑料容易老化,这会对其材料性能和表现产生负面影响。为确保这些材料的长期可用性,必须在实际使用环境中进行实时测试,以评估其降解情况。然而在实践中,通常采用加速老化技术以避免时间损耗。随着时间推移,塑料降解的各种指标逐渐显现,如分子量变化、开裂以及诸如断裂应变和冲击强度等机械性能的改变。其中,颜色劣化或变化是有助于评估这些材料使用寿命的关键因素。鉴于如今3D打印中塑料的使用日益增加,且在这些应用中对强度的关注超过美观度,基于颜色与强度之间的关系来评估塑料的老化情况尤为有用。3D打印在各行业的广泛应用使得了解老化条件下的材料性能成为必要。本研究考察了老化对三种不同颜色(黄色、橙色和红色)以及三种不同填充率(20%、60%和100%)的聚乳酸(PLA)机械性能的影响。样品经历了432小时的加速老化过程,包括8小时紫外线辐射、15分钟喷水,然后关闭紫外线灯3小时45分钟。对样品进行了拉伸试验、弯曲试验、硬度测量和颜色评估,将老化后的颜色变化与材料的机械性能联系起来。结果表明,老化后,填充率为100%的黄色样品的拉伸强度提高了6.9%(从44.50兆帕提高到47.58兆帕)。填充率为100%的橙色样品受老化影响较小,而所有填充率的红色样品的拉伸强度均有所下降。关于弯曲力,橙色、黄色和红色样品的弯曲力分别增加了10.37%、25.05%和8.87%。本研究强调了在设计用于长期应用的3D打印材料时颜色选择的重要性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/06dc/11643522/23f0031f1466/materials-17-05908-g001.jpg

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