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一种基于银/钯纳米颗粒功能化氧化锌纳米片的高性能氢气传感器。

A sigh-performance hydrogen gas sensor based on Ag/Pd nanoparticle-functionalized ZnO nanoplates.

作者信息

Nguyet To Thi, Thanh Le Dang Thi, Van Duy Nguyen, Xuan Chu Thi, Ingebrandt Sven, Vu Xuan Thang, Hoa Nguyen Duc

机构信息

International Training Institute for Materials Science (ITIMS), Hanoi University of Science and Technology (HUST) No 1 Dai Co Viet, Hai Ba Trung Ha Noi Vietnam

Institute of Materials in Electrical Engineering 1, RWTH Aachen University Sommerfeldstr. 24 Aachen 52074 Germany.

出版信息

RSC Adv. 2023 Apr 26;13(19):13017-13029. doi: 10.1039/d3ra01436c. eCollection 2023 Apr 24.

DOI:10.1039/d3ra01436c
PMID:37124013
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10132452/
Abstract

As a source of clean energy, hydrogen (H) is a promising alternative to fossil fuels in reducing the carbon footprint. However, due to the highly explosive nature of H, developing a high-performance sensor for real-time detection of H gas at low concentration is essential. Here, we demonstrated the H gas sensing performance of Ag/Pd nanoparticle-functionalized ZnO nanoplates. Bimetallic Ag/Pd nanoparticles with an average size of 8 nm were prepared and decorated on the surface of ZnO nanoplates to enhance the H gas sensing performance. Compared with pristine ZnO, the sensor based on ZnO nanoplate doped with Ag/Pd (0.025 wt%) exhibited an outstanding response upon exposure to H gas ( / = 78 for 500 ppm) with fast response time and speedy recovery. The sensor also showed excellent selectivity for the detection of H over the interfering gases (, CO, NH, HS, and VOCs). The superior gas sensing of the sensor was dominated by the morphological structure of ZnO, and the synergistic effect of strong adsorption and the optimum catalytic characteristics of the bimetallic Ag/Pd enhances the hydrogen response of the sensors. Thus, bimetallic Ag/Pd-doped ZnO is a promising sensing material for the quantitative determination of H concentration towards industrial applications.

摘要

作为一种清洁能源,氢气(H)在减少碳足迹方面是一种很有前景的化石燃料替代品。然而,由于氢气具有高度爆炸性,开发一种用于低浓度氢气实时检测的高性能传感器至关重要。在此,我们展示了银/钯纳米颗粒功能化的氧化锌纳米片的氢气传感性能。制备了平均尺寸为8纳米的双金属银/钯纳米颗粒,并将其修饰在氧化锌纳米片表面以增强氢气传感性能。与原始氧化锌相比,基于掺杂0.025 wt%银/钯的氧化锌纳米片的传感器在暴露于氢气时表现出出色的响应(500 ppm时/ = 78),响应时间快且恢复迅速。该传感器对氢气的检测还表现出优于干扰气体(、一氧化碳、氨气、硫化氢和挥发性有机化合物)的选择性。传感器卓越的气敏性能主要由氧化锌的形态结构决定,双金属银/钯的强吸附协同效应和最佳催化特性增强了传感器对氢气的响应。因此,双金属银/钯掺杂的氧化锌是一种有前景的传感材料,可用于工业应用中氢气浓度的定量测定。

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