Wang Fang-Hsing, Li An-Jhe, Liu Han-Wen, Kang Tsung-Kuei
Graduate Institute of Optoelectronic Engineering, National Chung Hsing University, Taichung 402202, Taiwan.
Department of Electrical Engineering, National Chung Hsing University, Taichung 402202, Taiwan.
Sensors (Basel). 2024 Sep 9;24(17):5852. doi: 10.3390/s24175852.
Photodetectors and gas sensors are vital in modern technology, spanning from environmental monitoring to biomedical diagnostics. This paper explores the UV detection and gas sensing properties of a zinc oxide (ZnO) nanorod array (ZNA) grown on silver nanowire mesh (AgNM) using a hydrothermal method. We examined the impact of different zinc acetate precursor concentrations on their properties. Results show the AgNM forms a network with high transparency (79%) and low sheet resistance (7.23 Ω/□). A sol-gel ZnO thin film was coated on this mesh, providing a seed layer with a hexagonal wurtzite structure. Increasing the precursor concentration alters the diameter, length, and area density of ZNAs, affecting their performance. The ZNA-AgNM-based photodetector shows enhanced dark current and photocurrent with increasing precursor concentration, achieving a maximum photoresponsivity of 114 A/W at 374 nm and a detectivity of 6.37 × 10 Jones at 0.05 M zinc acetate. For gas sensing, the resistance of ZNA-AgNM-based sensors decreases with temperature, with the best hydrogen response (2.71) at 300 °C and 0.04 M precursor concentration. These findings highlight the potential of ZNA-AgNM for high-performance UV photodetectors and hydrogen gas sensors, offering an alternative way for the development of future sensing devices with enhanced performance and functionality.
光电探测器和气体传感器在现代技术中至关重要,涵盖从环境监测到生物医学诊断等领域。本文探讨了采用水热法在银纳米线网格(AgNM)上生长的氧化锌(ZnO)纳米棒阵列(ZNA)的紫外探测和气体传感特性。我们研究了不同醋酸锌前驱体浓度对其性能的影响。结果表明,AgNM形成了具有高透明度(79%)和低方块电阻(7.23Ω/□)的网络。在该网格上涂覆了溶胶 - 凝胶ZnO薄膜,提供了具有六方纤锌矿结构的种子层。增加前驱体浓度会改变ZNA的直径、长度和面积密度,从而影响其性能。基于ZNA - AgNM的光电探测器随着前驱体浓度的增加,暗电流和光电流增强,在374nm处实现了114A/W的最大光响应度,在0.05M醋酸锌浓度下探测率达到6.37×10琼斯。对于气体传感,基于ZNA - AgNM的传感器电阻随温度降低,在300°C和0.04M前驱体浓度下对氢气的响应最佳(2.71)。这些发现突出了ZNA - AgNM在高性能紫外光电探测器和氢气传感器方面的潜力,为未来开发具有更高性能和功能的传感设备提供了一种替代方法。