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Ce:LYSO,从闪烁体到固态照明的蓝色荧光集中器。

Ce:LYSO, from scintillator to solid-state lighting as a blue luminescent concentrator.

机构信息

Université Paris-Saclay, Institut d'Optique Graduate School, CNRS, Laboratoire Charles Fabry, 91127, Palaiseau, France.

Université PSL, Chimie ParisTech, CNRS, Institut de Recherche de Chimie Paris, 75005, Paris, France.

出版信息

Sci Rep. 2023 May 3;13(1):7199. doi: 10.1038/s41598-023-32689-z.

Abstract

Cerium-doped lutetium-yttrium oxyorthosilicate (Ce:LYSO) is a well-known single crystal scintillator used in medical imaging and security scanners. Recent development of high power UV LED, matching its absorption band, questions the possibility to use Ce:LYSO in a new way: as LED-pumped solid-state light source. Since Ce:LYSO is available in large size crystals, we investigate its potential as a luminescent concentrator. This paper reports an extensive study of the performance in close relation to the spectroscopic properties of this crystal. It gives the reasons why the Ce:LYSO crystal tested in this study is less efficient than Ce:YAG for luminescent concentration: limited quantum efficiency and high losses coming from self-absorption and from excited-state absorption are playing key roles. However, we demonstrate that a Ce:LYSO luminescent concentrator is an innovative source for solid-state lighting. Pumped by a peak power of 3400 W in quasi-continuous wave regime (40 µs, 10 Hz), a rectangular (1 × 22 × 105 mm) Ce:LYSO crystal delivers a broadband spectrum (60 nm FWHM) centered at 430 nm. At full output aperture (20 × 1 mm), it emits a peak power of 116 W. On a squared output surface (1 × 1 mm) it emits 16 W corresponding to a brightness of 509 W cm sr. This combination of spectrum power and brightness is higher than blue LEDs and opens perspectives for Ce:LYSO in the field of illumination namely for imaging.

摘要

掺铈硅酸钇镥(Ce:LYSO)是一种著名的单晶闪烁体,用于医学成像和安全扫描仪。最近高功率紫外 LED 的发展,与它的吸收带相匹配,使得人们质疑是否可以以新的方式使用 Ce:LYSO:作为 LED 泵浦的固态光源。由于 Ce:LYSO 可提供大尺寸晶体,因此我们研究了它作为发光集中器的潜力。本文报道了一项与该晶体光谱特性密切相关的性能的广泛研究。它给出了在这项研究中测试的 Ce:LYSO 晶体效率不如 Ce:YAG 用于发光集中的原因:有限的量子效率和来自自吸收和激发态吸收的高损耗起着关键作用。然而,我们证明了 Ce:LYSO 发光集中器是固态照明的一种创新光源。在准连续波模式(40 μs,10 Hz)下,峰值功率为 3400 W 激发时,一个矩形(1×22×105mm)Ce:LYSO 晶体可提供中心波长为 430nm、带宽为 60nm(半高全宽)的宽带光谱。在全输出孔径(20×1mm)下,它可输出 116W 的峰值功率。在方形输出表面(1×1mm)上,它可输出 16W 的光,亮度为 509W cm sr。这种光谱功率和亮度的组合高于蓝色 LED,为 Ce:LYSO 在照明领域(例如成像)开辟了前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3a53/10156901/9a23b6261351/41598_2023_32689_Fig1_HTML.jpg

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