Kusuma Jefry, Indartono Yuli S, Mujahidin Didin
Faculty of Mechanical and Aerospace Engineering, Bandung Institute of Technology, Bandung, Indonesia.
Faculty of Mathematics and Natural Science, Bandung Institute of Technology, Bandung, Indonesia.
MethodsX. 2023 Apr 14;10:102185. doi: 10.1016/j.mex.2023.102185. eCollection 2023.
This study aims to analyze the potential and characteristics of biodiesel and activated carbon from spent coffee grounds (SCG).•Biodiesel was obtained by extracting oil from SCG using Soxhlet extraction method with n-hexane solvent with an oil yield of 18.14% w/w of dry SCG. Furthermore, the coffee oil was esterified and transesterified to produce biodiesel with 57.32 % yield of coffee oil and higher heating value of 36.69 MJ/kg, density (15°C) of 0.89 g/mL, kinematic viscosity (40°C) of 7.67 mm/s, acid number of 1.19 mg KOH/g oil.•The residue in form of grounds after oil extraction process was turned into activated carbon using two step activation process. Carbonization process was carried out at 500, 600, 700, and 800°C for 30 minutes and then chemically activated using potassium hydroxide (KOH) at 750°C for 2 hours. As the comparison, activated carbon was also made from SCG without oil extraction process. This study shows that the adsorption capacity of activated carbon made from SCG with oil extraction was better than without oil extraction. The best adsorption of activated carbon was obtained from SCG with oil extraction and carbonized at 700°C with iodine value of 1,224.59 mg/g and methylene blue value of 153.08 mg/g.
本研究旨在分析废弃咖啡渣(SCG)制备生物柴油和活性炭的潜力及特性。
通过索氏提取法,使用正己烷溶剂从SCG中提取油脂来制备生物柴油,干SCG的油脂产率为18.14%(w/w)。此外,将咖啡油进行酯化和酯交换反应以生产生物柴油,咖啡油产率为57.32%,高热值为36.69 MJ/kg,密度(15°C)为0.89 g/mL,运动粘度(40°C)为7.67 mm/s,酸值为1.19 mg KOH/g油。
油提取过程后剩余的咖啡渣形式的残渣通过两步活化工艺转化为活性炭。碳化过程在500、600、700和800°C下进行30分钟,然后在750°C下用氢氧化钾(KOH)进行2小时的化学活化。作为对比,也从未经油提取过程的SCG制备了活性炭。本研究表明,经油提取的SCG制备的活性炭的吸附能力优于未经油提取的。从经油提取并在700°C碳化的SCG获得的活性炭吸附效果最佳,碘值为1224.59 mg/g,亚甲蓝值为153.08 mg/g。