School of Chemical and Minerals Engineering, North-West University, Potchefstroom Campus, Private Bag X6001, Potchefstroom 2520, South Africa.
Waste Manag. 2018 Feb;72:240-254. doi: 10.1016/j.wasman.2017.10.042. Epub 2017 Nov 14.
Spent coffee grounds are composed of lipid, carbohydrates, carbonaceous, and nitrogen containing compounds among others. Using n-hexane and n-hexane/isopropanol mixture highest oil yield was achived during soxhlet extraction of oil from spent coffee grounds. Alternatively, supercritical carbon dioxide can be employed as a green solvent for the extraction of oil. Using advanced chemical and biotechnological methods, spent coffee grounds are converted to various biofuels such as, biodiesel, renewable diesel, bioethanol, bioethers, bio-oil, biochar, and biogas. The in-situ transesterification of spent coffee grounds was carried out in a large scale (4 kg), which led to 80-83% biodiesel yield. In addition, a large number of value added and diversified products viz. polyhydroxyalkanoates, biosorbent, activated carbon, polyol, polyurethane foam, carotenoid, phenolic antioxidants, and green composite are obtained from spent coffee grounds. The principles of circular economy are applied to develop a sustanaible biorefinery based on valorisation of spent coffee grounds.
用过的咖啡渣含有脂质、碳水化合物、含碳和含氮化合物等。在索氏提取法中,使用正己烷和正己烷/异丙醇混合物可以从用过的咖啡渣中提取出最高的油产量。或者,可以使用超临界二氧化碳作为提取油的绿色溶剂。用过的咖啡渣可以通过先进的化学和生物技术转化为各种生物燃料,如生物柴油、可再生柴油、生物乙醇、生物醚、生物油、生物炭和沼气。用过的咖啡渣在大规模(4kg)的原位酯交换反应中,得到了 80-83%的生物柴油产量。此外,还可以从用过的咖啡渣中获得大量附加值和多样化的产品,如聚羟基烷酸酯、生物吸附剂、活性炭、多元醇、聚氨酯泡沫、类胡萝卜素、酚类抗氧化剂和绿色复合材料。循环经济的原则被应用于开发基于废咖啡渣增值的可持续生物精炼厂。