Zhang Wei, Shang Xin, Chen Xiaoxuan, Chen Shenggui, Liu Zhengliang, Zhang Lijuan
Institute of Science & Technology Innovation, Dongguan University of Technology, Dongguan 523820, China.
School of Materials Science and Engineering, Tianjin University, Tianjin 300350, China.
Materials (Basel). 2023 Apr 28;16(9):3443. doi: 10.3390/ma16093443.
For exploring an effective heat treatment schedule to enhance the strength-plasticity balance of the ferrite-austenite 12CrNi2 alloy steel additively manufactured by directed energy deposition (DED), 12CrNi2 was heat-treated with deliberately designed direct quenching (DQ) and cyclic quenching (CQ), respectively, and the differently quenched steels were then tempered at a temperature from 200 °C to 500 °C. It was found that the CQ, in contrast to the DQ, led the 12CrNi2 to have significantly increased tensile strength without losing its plasticity, based on the introduction of fine-grained lath martensite and the {112}<111>-type nanotwins. The nanotwins were completely degenerated after the 200 °C tempering. This led the CQ-treated steel to decrease in not only its tensile strength, but also its plasticity. In addition, an interesting phenomenon observed was that the DQ-induced laths and rod-like precipitates, and the tempering-induced laths and rod-like precipitates were all prone to be generated along the {112} planes of the martensitic crystal (α-Fe), which were exactly fitted with the {112}-type crystalline orientation of the long or short nanotwins in the CQ-induced martensite. The quenching-tempering-induced generation of the {112}-orientated laths and rod-like precipitates was explicated in connection with the {112}<111>-type long or short nanotwins in the CQ-induced lath martensite.
为探索一种有效的热处理工艺,以增强通过定向能量沉积(DED)增材制造的铁素体-奥氏体12CrNi2合金钢的强度-塑性平衡,分别对12CrNi2进行了精心设计的直接淬火(DQ)和循环淬火(CQ)处理,然后将不同淬火的钢在200℃至500℃的温度下回火。结果发现,与DQ相比,CQ使12CrNi2在不损失塑性的情况下显著提高了抗拉强度,这是由于引入了细晶板条马氏体和{112}<111>型纳米孪晶。纳米孪晶在200℃回火后完全退化。这导致经CQ处理的钢不仅抗拉强度降低,而且塑性也降低。此外,观察到一个有趣的现象是,DQ诱导的板条和棒状析出物以及回火诱导的板条和棒状析出物都倾向于沿马氏体晶体(α-Fe)的{112}面生成,这与CQ诱导马氏体中长或短纳米孪晶的{112}型晶体取向完全吻合。结合CQ诱导板条马氏体中的{112}<111>型长或短纳米孪晶,解释了淬火-回火诱导的{112}取向板条和棒状析出物的生成。