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二元Cu-Sc合金冷变形对析出动力学影响的差示扫描量热分析

DSC Analysis of the Effect of Cold Deformation on the Precipitation Kinetics of a Binary Cu-Sc Alloy.

作者信息

Henle Ramona, Dölling Julia, Prahl Ulrich, Nandi Gerrit, Zilly Andreas

机构信息

Faculty of Technology, Cooperative State University Heidenheim, Marienstraße 20, 89518 Heidenheim an der Brenz, Germany.

Faculty of Technology, Cooperative State University Stuttgart, Lerchenstraße 1, 70197 Stuttgart, Germany.

出版信息

Materials (Basel). 2023 Apr 29;16(9):3462. doi: 10.3390/ma16093462.

Abstract

The present study aimed to investigate the effect of cold deformation on the precipitation kinetics of a binary CuSc alloy containing 0.4 wt.% scandium using the experimental analysis method of differential scanning calorimetry (DSC). Non-deformed and 75% cross-section-reduced cold-rolled supersaturated specimens were tested in non-isothermal DSC runs at up to five different heating rates. The DSC results showed that cold rolling significantly accelerated the precipitation process in the binary alloy, leading to a decrease in the initial and peak temperatures of the exothermic reactions. The activation energies calculated with the Kissinger method indicated that the precipitation activation energy decreased with increasing cold deformation. The findings of this study provide worthy implications to further optimize the processing of Cu-Sc alloys with improved mechanical properties.

摘要

本研究旨在采用差示扫描量热法(DSC)实验分析方法,研究冷变形对含0.4 wt.%钪的二元CuSc合金析出动力学的影响。对未变形和横截面缩减75%的冷轧过饱和试样在高达五种不同加热速率的非等温DSC实验中进行测试。DSC结果表明,冷轧显著加速了二元合金中的析出过程,导致放热反应的起始温度和峰值温度降低。用基辛格方法计算的活化能表明,析出活化能随冷变形量的增加而降低。本研究结果为进一步优化具有改善力学性能的Cu-Sc合金加工工艺提供了有价值的启示。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1ac1/10179944/b966f8de49fd/materials-16-03462-g0A1.jpg

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