Constantin Carolina, Stefan Daniela Simina, Manea-Saghin Ana-Maria, Meghea Irina
Department of Inorganic Chemistry, Physical Chemistry and Electrochemistry, Faculty of Chemical Engineering and Biotechnologies, University Politehnica of Bucharest, 1-7 Polizu Str., 011061 Bucharest, Romania.
Department of Analytical Chemistry and Environmental Engineering, Faculty of Chemical Engineering and Biotechnologies, University Politehnica of Bucharest, 1-7 Polizu Str., 011061 Bucharest, Romania.
Polymers (Basel). 2023 Apr 27;15(9):2085. doi: 10.3390/polym15092085.
Improving soil quality is of growing interest and, among optimal solutions, the reuse and recycling of biopolymers of pelt waste from the tannery industry have been proposed, one of them being for collagen hydrolysate with micronutrients and polymers incorporated, to be used as fertilizers for poor soils rehabilitation. As functionalization agents, polyacrylamide, starch and dolomite were included into biopolymer matrixes in order to enhance their specific efficiency. These fertilizers were adequately characterized for their physical-chemical properties, including nutrient content, and tested on three poor soils, while a fourth sample of normal soil was chosen for comparative purposes. These soils were also characterized for their texture and physical-chemical properties in order to establish the fertility state of the soils as a function of nutrient content. In this respect, a series of agrochemical tests were developed at laboratory scale, simulating real agriculture environments in a vegetation room, where a significant plant growth in height was observed for all the agro-hydrogels with nutrients encapsulated, and multiplication of the nodosities number was observed in the case of the soybean culture. The most significant effect was obtained in the case of the fertilizer functionalized with starch. Finally, the application dose of the organic fertilizers for specific culture plants was estimated, such as field cultures (cereals, corn), field vegetables, vineyards or fruit-growing plantations. These agro-collagen fertilizers are particularly recommended for amendment of field cereals and vegetables. The novelty of this study mainly consists of the recovery and recycling of the pelt waste as efficient fertilizers after their adequate functionalization with synthetic or natural biopolymers.
提高土壤质量越来越受到关注,在最佳解决方案中,有人提出对制革工业的兽皮废料生物聚合物进行再利用和回收,其中之一是将含有微量营养素和聚合物的胶原蛋白水解物用作贫瘠土壤修复的肥料。作为功能化剂,聚丙烯酰胺、淀粉和白云石被纳入生物聚合物基质中,以提高其特定效率。对这些肥料的物理化学性质进行了充分表征,包括养分含量,并在三种贫瘠土壤上进行了测试,同时选择了第四种正常土壤样本用于比较。还对这些土壤的质地和物理化学性质进行了表征,以便根据养分含量确定土壤的肥力状态。在这方面,在实验室规模上开展了一系列农业化学测试,在植物生长室模拟真实农业环境,观察到所有包封有养分的农业水凝胶使植物高度显著增加,大豆种植中根瘤数量增加。在用淀粉功能化的肥料中获得了最显著的效果。最后,估算了特定栽培植物(如大田作物(谷物、玉米)、大田蔬菜、葡萄园或果树种植园)的有机肥料施用量。这些农业胶原蛋白肥料特别推荐用于改良大田谷物和蔬菜。本研究的新颖之处主要在于,将兽皮废料经过与合成或天然生物聚合物充分功能化后回收再利用为高效肥料。