Departamento de Química, Universidade Federal de Lavras, Caixa Postal 3037, CEP 37200-000, Lavras-MG, Brazil.
J Hazard Mater. 2010 Apr 15;176(1-3):374-80. doi: 10.1016/j.jhazmat.2009.11.040. Epub 2009 Nov 13.
The feasibility of using a solid waste (rich in nitrogen) from the leather industry, after chromium extraction, as adsorbent for P and K, for possible utilization as NPK fertilizer was evaluated. The materials, with and without the addition of P and K, were characterized by chemical analyses, infrared spectroscopy, EDS (energy dispersive X-ray spectrometry) and SEM (scanning electronic microscopy). Langmuir and Freundlich equations were used for analyzing the experimental data, which showed a better fit to the Freundlich model, thus suggesting a multilayer adsorption process on the surface of the adsorbent. A preliminary test in greenhouse demonstrates that the P and K incorporation on the matrix rich in nitrogen (collagen) is a interesting alternative to use such material as NPK fertilizer. The application of N(collagen)PK formulations, as a source of nutrients for the growth of rice plants, showed promising agronomic results.
评估了从皮革工业中提取铬后的富含氮的固体废物作为 P 和 K 吸附剂,以可能用作 NPK 肥料的可行性。对添加和不添加 P 和 K 的材料进行了化学分析、红外光谱、EDS(能谱仪)和 SEM(扫描电子显微镜)的表征。使用 Langmuir 和 Freundlich 方程分析了实验数据,结果表明 Freundlich 模型更适合,因此表明吸附剂表面存在多层吸附过程。温室初步试验表明,将 P 和 K 掺入富含氮(胶原蛋白)的基质中是将此类材料用作 NPK 肥料的一种有趣选择。N(胶原蛋白)PK 配方作为水稻生长的营养源的应用显示出有希望的农业结果。