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城市化海岸和河口海域中双酚类似物的发生、分布及生态风险。

Occurrence, distribution, and ecological risk of bisphenol analogues in marine ecosystem of urbanized coast and estuary.

机构信息

International Institute of Aquaculture and Aquatic Sciences, Universiti Putra Malaysia, 71050 Port Dickson, Negeri Sembilan, Malaysia.

Department of Environment, Faculty of Forestry and Environment, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia.

出版信息

Mar Pollut Bull. 2023 Jul;192:115019. doi: 10.1016/j.marpolbul.2023.115019. Epub 2023 May 16.

Abstract

Bisphenol analogues are prevalent globally because of rampant usage and imprecise processing techniques, prompting alerts about environmental and health hazards. The method employed in this study by solid phase extraction (SPE) and liquid chromatography-tandem quadrupole mass spectrometer (LC-MS/MS) for both quantification and qualitative analysis of the bisphenol compounds in the surface water samples. The coastal and estuarine surface water of Port Dickson and Lukut ranges from 1.32 ng/L to 1890.51 ng/L of bisphenol analogues. BPF mean concentration at 1143.88 ng/L is the highest, followed by BPA and BPS at 59.01 ng/L and 10.96 ng/L, respectively. Based on RQm for bisphenol analogues, the highest for BPF at 2.49 (RQ > 1, high risk), followed by BPS at 0.12 (0.1 < RQ < 1, medium risk) and BPA at 0.09 (0.1 < RQ < 1, medium risk). The presence and current risk of bisphenols analogues should alert the possible water quality degradation soon.

摘要

双酚类似物在全球范围内广泛存在,这是由于其广泛的使用和不精确的处理技术,引起了人们对环境和健康危害的警惕。本研究采用固相萃取(SPE)和液相色谱-串联四极杆质谱(LC-MS/MS)相结合的方法,对地表水中的双酚化合物进行定量和定性分析。研究表明,在波德申和卢古地区的沿海和河口地表水样本中,双酚类似物的浓度范围为 1.32ng/L 至 1890.51ng/L。BPF 的平均浓度最高,为 1143.88ng/L,其次是 BPA 和 BPS,分别为 59.01ng/L 和 10.96ng/L。根据双酚类似物的 RQm 值,BPF 的最高值为 2.49(RQ>1,高风险),其次是 BPS 的 0.12(0.1<RQ<1,中风险)和 BPA 的 0.09(0.1<RQ<1,中风险)。双酚类似物的存在及其当前的风险应引起人们对可能的水质恶化的警惕。

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