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生物纳米驱油体系的合成及其提高采收率潜力

Synthesis and Enhanced Oil Recovery Potential of the Bio-Nano-Oil Displacement System.

作者信息

Wang Bo, Wang Shunping, Yan Huaxue, Bai Yangsong, She Yuehui, Zhang Fan

机构信息

School of Energy Resources, China University of Geosciences (Beijing), Beijing 100083, China.

College of Petroleum Engineering, Yangtze University, Wuhan, Hubei 430100, China.

出版信息

ACS Omega. 2023 May 5;8(19):17122-17133. doi: 10.1021/acsomega.3c01447. eCollection 2023 May 16.

Abstract

Nanoparticles (NPs) have attracted great attention in the tertiary oil recovery process due to their unique properties. As an economical and efficient green synthesis method, biosynthesized nanoparticles have the advantages of low toxicity, fast preparation, and high yield. In this study, with the theme of biotechnology, for the first time, the bio-nanoparticles reduced by iron-reducing bacteria were compounded with the biosurfactant produced by to form a stable bio-nano flooding system, revealing the oil flooding mechanism and enhanced oil recovery (EOR) potential of the bio-nano flooding system. The interfacial properties of the bio-nano-oil displacement system were studied by interfacial tension and wettability change experiments. The enhanced oil recovery potential of the bio-nano-oil displacement agent was measured by microscopic oil displacement experiments and core flooding experiments. The bio-nano-oil displacement system with different nanoparticle concentrations can form a stable dispersion system. The oil-water interfacial tension and contact angle decreased with the increase in concentration of the bio-nano flooding system, which also has a high salt tolerance. Microscopic oil displacement experiments proved the efficient oil displacement of the bio-nano-oil displacement system and revealed its main oil displacement mechanism. The effects of concentration and temperature on the recovery of the nano-biological flooding system were investigated by core displacement experiments. The results showed that the recovery rate increased from 4.53 to 15.26% with the increase of the concentration of the system. The optimum experimental temperature was 60 °C, and the maximum recovery rate was 15.63%.

摘要

纳米颗粒(NPs)因其独特的性质在三次采油过程中引起了极大的关注。作为一种经济高效的绿色合成方法,生物合成的纳米颗粒具有低毒性、制备快速和高产率的优点。在本研究中,以生物技术为主题,首次将铁还原细菌还原的生物纳米颗粒与[具体细菌名称]产生的生物表面活性剂复合,形成稳定的生物纳米驱油体系,揭示了生物纳米驱油体系的驱油机理和提高采收率(EOR)潜力。通过界面张力和润湿性变化实验研究了生物纳米驱油体系的界面性质。通过微观驱油实验和岩心驱替实验测定了生物纳米驱油剂的提高采收率潜力。不同纳米颗粒浓度的生物纳米驱油体系可形成稳定的分散体系。随着生物纳米驱油体系浓度的增加,油水界面张力和接触角减小,该体系还具有较高的耐盐性。微观驱油实验证明了生物纳米驱油体系的高效驱油性能,并揭示了其主要驱油机理。通过岩心驱替实验研究了浓度和温度对纳米生物驱油体系采收率的影响。结果表明,随着体系浓度的增加,采收率从4.53%提高到15.26%。最佳实验温度为60℃,最大采收率为15.63%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7873/10193539/d3f23921163b/ao3c01447_0003.jpg

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